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Corresponding Author

Shuhua Ma

Abstract

The carbon powders and film electrode with core shell structure were prepared by carbonization in gas state with using refined coal as shell material and Artificial Graphite and Mesocarbon Microbeads (2 800 ℃) graphite as core material. Galvanostatic charge/discharge measurement showed that both steady charge/discharge capacity and first charge/discharge efficiency were improved. Cyclic voltammetry indicated that the peak at about 0.7 V vs. Li +/Li characteristic of decomposition of electrolyte got weakened, and a more compact film was formed. X ray diffraction measurement suggested the existence of amorphous carbon shell on the carbon powders and carbon film.

Keywords

Lithium ion battery, Carbon material, Anode, Modification, Core shell structure

Publication Date

1997-02-28

Online Available Date

1997-02-28

Revised Date

1997-02-28

Received Date

1997-02-28

References

1马树华.作为锂离子电池负极的碳材料的结构、性能与改性(博士学位论文).中国科学院长春应用化学研究所,1996,52汪继强.第六届国际锂电池会议及德国参观综述.成都:第二十届全国化学与物理电源会议论文集(摘要),1992:2323KuribayashiI,YokoyamaM,YamashitaM.SeventhInternationalMeetingonLithiumBatteries.Boston,Massachusets,USA,May15-20,1994,ExtendedAbstracts:14大谷杉郎,真田雄三著,张名大,杨俊英译.炭化工学基础.中科院沈阳金属研究所,兰州炭素厂研究所,1985:43

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