Electrochemical Synthesis and Characterization of Ba-Pb-O and Bi-Pb-O Oxides

Authors

Min Xie, Inst of Chem., Academy Sinica, Beijing 100080
Liangzhong Zhao, Inst of Chem., Academy Sinica, Beijing 100080
Cuiying Xu, Inst of Chem., Academy Sinica, Beijing 100080
Jinbiao Zhang, Inst of Chem., Academy Sinica, Beijing 100080

Corresponding Author

Min Xie

Abstract

Pb-based oxides Ba-Pb-O and Bi-Pb-O were synthesized from aqueous solutions by using electrochemical method. The resulting Ba-Pb-O and Bi-Pb-O were characterized using XPS, EDX and XRD. The results show that perovskite BaPb_0.9O₃ can be electrodeposited on the anode only from strong alkaline solution. In acid aqueous solution, conducting BiPb₂O_z oxide is fromed on the anode. In these oxides the nominal valence of lead is +4.

Keywords

Pb-based oxides, Electrchemical synthesis, Characterization

DOI Link

https://doi.org/10.61558/2993-074X.2651

Publication Date

1997-02-28

Online Available Date

1997-02-28

Revised Date

1996-10-03

Received Date

1996-07-09

Recommended Citation

Min Xie, Liangzhong Zhao, Cuiying Xu, Jinbiao Zhang. Electrochemical Synthesis and Characterization of Ba-Pb-O and Bi-Pb-O Oxides[J]. Journal of Electrochemistry, 1997 , 3(1): 72-75.
DOI: 10.61558/2993-074X.2651
Available at: https://jelectrochem.xmu.edu.cn/journal/vol3/iss1/4