Abstract
Pb based oxides Ba Pb O and Bi Pb O were synthesized from aqueous solutions by using electrochemical method. The resulting Ba Pb O and Bi Pb O were characterized using XPS, EDX and XRD. The results show that perovskite BaPb 0.9 O 3 can be electrodeposited on the anode only from strong alkaline solution. In acid aqueous solution, conducting BiPb 2O z oxide is fromed on the anode. In these oxides the nominal valence of lead is +4.
Publication Date
1997-02-28
Online Available Date
1997-02-28
Revised Date
1997-02-28
Received Date
1997-02-28
Recommended Citation
Min Zhao Liangzhong Xie, Cuiying Xu, Jinbiao Zhang.
Electrochemical Synthesis and Characterization of Ba Pb O and Bi Pb O Oxides[J]. Journal of Electrochemistry,
1997
,
3(1): Article 4.
DOI: 10.61558/2993-074X.2651
Available at:
https://jelectrochem.xmu.edu.cn/journal/vol3/iss1/4
References
1YasunobuInoue,HiroyukiSano,KazunoriSato.Catalyticpropertiesofperovskiteoxides,BaPb1-xBixO3,foroxidativecouplingreactionofmethane.J.Mater.Sci.Let.,1989,8:172SleightAW,GilsonJL,BierstedtPE.High-temperaturesuperconductivityintheBaPb1-xBixO3,sys-tem.SolidStateCommunications,1975,17:273BoivinJC,ThomasD,CanonneJetal.Newcathodematerialsforlithiumbatteries:Leadbismuthmixedoxides.Mater.Res.Bul.,1987,22(3):2854DumelieM,NowogrockiG,BoivinJC.Ionicconductormembraneforoxygenseperation.SolidStateIonics,1988,28-30:5245JamesGJr,VictorG,YoungJretal.ApplicationofanelectrochemicalquartzcrystalmicrobalancetoastudyoftheanodicdepositionofPbO2andBi-PbO2filmsongoldelectrodes.J.Electrochem.Soc.,1994,141:6526NitaT,NagaseK,HayakawaSetal.Formationandpropertiesofbariummetaplumbata.J.Amer.Ce-ram.Soc.,1965,48:6427BordovskiGA,AnisimovaNI,AvenesyanVT.Preparationandstudyofelectrophysicalpropertiesofsomeleadoxidebismuthoxidesystemcompounds.Izv.Akad.NaukSSSR,Neorg.Mater.,1981,17(2):2918YeoIH,SangsooK,RobertJetal.Electrocatalysisofanodicoxygentransferreactions:Comparisionofstructuraldatawithelectrocatalyticphenomenaforbismuth-dopedleaddioxide.J.Electrochem.Soc.,1989,136:13959PowderDifractionFile,Sets11-15.PrintedinPhiladeiphia:PublishedbytheJointCommiteeonPow-derDifractionStandards,1972:37310Powderdifractionfile,Set41.PrintedinPhiladelphia:PublishedbytheInternationalCenterforDifractionData,1991:60411WagnerCD,RiggsWM,DavisLEetal.HandbookofX-rayPhotoelectronSpectroscopy.PrintedinU.S.A.:PublishedbyPerkin-ElmerCorporation,1979:16012ZhaoLZ,ZhangJB.BiandOvalencesinBa-K-Bi-O(M=Rb,La,Eu,In,TlandPb)andtherelatedcompounds.SolidStateCommunications,1994,90:70913KharasKCC,LunsfordJH.CatalyticpartialoxidationofmethaneoverBaPbO3:possibleinvolvementofperoxideion.J.Am.Chem.Soc.,1989,111:2336
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