Abstract
The polarographic and voltammetric behaviour of Cu(Ⅱ) xanthosine complex has been studied. A new sharp reduction peak is yielded at the potential of -0.14 V(vs, Ag/AgCl). The conc. of Cu(Ⅱ) is proportional to peak current of NPP in the range of 1×10 -6 ~1×10 -4 mol/L when the conc. of xanthosine is 1×10 -4 mol/L. It is indicated that the current has adsorption character. The mechanism of the electrode reaction was deduced and the ratio of the complex is Cu(Ⅱ) ∶ xanthosine=1∶1.
Keywords
Cu(Ⅱ) Xanthosine, Complex, Polarography
Publication Date
1997-05-28
Online Available Date
1997-05-28
Revised Date
1997-05-28
Received Date
1997-05-28
Recommended Citation
Huizhi Fan, Jinlong Liu, Jinghao Pan.
Study on Polarographic and Voltammetric Behaviour of Cu(Ⅱ) Xanthosine Complex[J]. Journal of Electrochemistry,
1997
,
3(2): Article 14.
DOI: 10.61558/2993-074X.3117
Available at:
https://jelectrochem.xmu.edu.cn/journal/vol3/iss2/14
References
1华东化工学院主编.生化药物(《药品集》第七分册).上海:上海科学技术出版社,1984:852PenumatikisG,HadjiliadisN,TheophanidesT.Complexesofinosine,cytidine,andguanosinewithpal-ladinum(Ⅱ).Inorg.Chem.,1978,17(4):915~9223NelsonHC.Anovelseriesofhydroxyl-bridgedCu(Ⅱ)-nucleosidecomplexes.J.Inorg.Nucl.Chem.,1979,41(11):1843~18454ChaoYen-YauH,KearnsDR.Magneticresonancestudiesofcopper(Ⅱ)interactionwithnuoleosidesandnuoleotides.J.Amer.Chem.Soc.,1977,99(19):6425~64345BardAJ,FaulknerLR.著,谷林瑛等译.电化学方法.北京:化学工业出版社,1988:1126阎锋,韩可心.电化学分析.辽宁:辽宁大学出版社,1994:278~280