Abstract
The performance of electrochemical reaction by which 1, 5-dinitroan-thraquinone is reduced to 1, 5-diam ino-4, 8-dihydroxyanthraquinone in sulfuric acid solution
at amalgamated copper electrode was investigated by cyclic voltammetry, steady-state polarization and constant potential electrolysis. The result shows that the electroreduction process of 1,5-DNA is characterized by strong adsorption of reactant, subsequent irreversible chemical reaction at amalgamated copper electrode in 12.75 mol/L H2SO4 at 140℃. The electrolytic product is verified to be 1,5-DA-4,8-DHA by infra-red spectrogram, the current efficient is 78% and yield of 1,5-DA-4,8-DHA is 72%. Moreover, the experment showed that the direct electroreduction depended on electrode materials, acid strength, additives, reactant concentration and so on.
Keywords
1, 5-Dinitroanthraquinone, Electrochemical reduction, 1, 5-Diamino-4, 8-Dihydroxyanthraquinone
Creative Commons License
This work is licensed under a Creative Commons Attribution 4.0 International License.
Publication Date
1997-05-28
Online Available Date
1997-05-28
Revised Date
1997-01-13
Received Date
1996-10-04
Recommended Citation
Chunan Ma, Shaoping Tong, Xiaoping Gao, Genbao Chen.
A Study of Electrochemical Reduction of 1,5-Dinitroanthraquinone to 1,5-Diamino-4,8-dihydroxyanthraquinone[J]. Journal of Electrochemistry,
1997
,
3(2): 160-167.
DOI: 10.61558/2993-074X.3560
Available at:
https://jelectrochem.xmu.edu.cn/journal/vol3/iss2/20
