Study on the Diffusion of Electroactive Molecules in Polymer Electrolyte by Microelectrode Voltammetry

Authors

Liming Ding
Shaojun Dong
Erkang Wang

Abstract

The ten years study on the diffusion of electroactive molecules in polymer electrolyte by microelectrode voltammetry was reviewed by considering the development background of polymer electrolyte materials. The classification, fabrication, applications and electrochemical measurements of microelectrode were introduced concisely. The several important factors influencing the diffusion of electroactive molecules were stressed. In the final part of this paper, some new reports on the diffusion of labeled molecules were introduced. 52 references were quoted.

Keywords

Polymer electrolyte, Electroactive molecules, Diffusion, Microelectrode, Voltammetry

DOI Link

https://doi.org/10.61558/2993-074X.3120

Publication Date

1997-08-28

Online Available Date

1997-08-28

Revised Date

1997-08-28

Received Date

1997-08-28

Recommended Citation

Liming Ding, Shaojun Dong, Erkang Wang. Study on the Diffusion of Electroactive Molecules in Polymer Electrolyte by Microelectrode Voltammetry[J]. Journal of Electrochemistry, 1997 , 3(3): Article 2.
DOI: 10.61558/2993-074X.3120
Available at: https://jelectrochem.xmu.edu.cn/journal/vol3/iss3/2

References

1ArmandMB，SanchezJY，GauthierM，ChoqueteY．InElectrochemistryofNovelMaterials．LipkowskiJ，RossPN．Eds．NewYork：VCHPublishers，1994：652GrayFM．SolidPolymerElectrolytes．NewYork：VCHPublishers，19913BlonskyPM，ShriverDF，AustinP，AlcockHR．Polyphosphazenesolidelectrolytes．J．Am．Chem．Soc．，1984，106：68544丁黎明．梳状高分子固体电解质的离子导电性研究．电化学，1996，2（3）：2995WatanabeM，SanuiK，OgataN．Correlationbetweenionicconductivityandthedynamicmechanicalproper－tyofpolymercomplexesformedbyasegmentedpolyetherpoly（urethaneurea）andlithiumperchlorate．Macromolecules，1986，19：8156WatanabeM，NaganoS，SanuiK，OgataN．Ionicconductivityofnetworkpolymersfrompoly（ethyleneox－ide）containinglithiumperchlorate．Polym．J．，1986，18：8097AloinF，SanchezJY，ArmandM．Electrochemicalbehavioroflithiumelectrolytesbasedonnewpolyethernetworks．J．Electrochem．Soc．，1994，141：19158BenrabahD，SylaS，SanchezJY，ArmandM．Cationicconductivityinpoly（oxyethyleneoxide）networks．J．PowerSources，1995，54：4569TakeokaS，OhnoH，TsuchidaE．Recentadvancementofion－conductivepolymers．Polym．Adv．Techn．，1993，4：5310BerthierC，GoreckiW，MinierM，ArmandM，ChabagnoJM，RigaudP．Microscopicinvestigationofion－icconductivityinalkalimetalsalts－poly（ethyleneoxide）adducts．SolidStateIonics，1983，11：9111MacCalumJR，VincentCA．Eds．PolymerElectrolytesReviews，Vol．1．Amsterdam：Elsevier，198712丁黎明．交替马来酸酐共聚物多缩乙二醇酯盐络合物的离子导电性（Ⅲ）．材料研究学报，1995，9（2）：18313DaytonMA，BrownJC，StutsKJ，WightmanRM．Faradaicelectrochemistryatmicrovoltammetricelectrodes．Anal．Chem．，1980，52：94614WightmanRM．Voltammetrywithmicroscopicelectrodesinnewdomains．Science，1988，240：41515MontenegroMI，PletcherD．Thedeterminationofthekineticsofelectrontransferusingfastsweepcyclicvoltammetryatmicrodiscelectrodes．J．Electroanal．Chem．，1986，200：37116OldhamKB，ZoskiCG，BondAM，SweigartDA．Measurementofultrafastelectrodekineticsviasteady－statevoltammogramsatmicrodiscelectrodes．J．Electroanal．Chem．，1988，248：46717AndrieuxCP，GarreauD，HapiotP，SaveantJM．Ultramicroelectrodes：cyclicvoltammetryaboveonemilionVs－1．J．Electroanal．Chem．，1988，248：44718HowelJO，WightmanRM．Ultrafastvoltammetryofanthraceneand9，10－diphenylanthracene．J．Phys．Chem．，1984，88：391519WightmanRM，MayLJ，MichaelAC．Detectionofdopaminedynamicsinthebrain．Anal．Chem．，1988，60：769A20WalingfordRA，EwingAG．Capilaryzoneelectrophoresiswithelectrochemicaldetectionin12．7μmdi－ametercolumns．Anal．Chem．，1988，60：197521ReedRA，GengL，MurrayRW．Solidstatevoltammetryofelectroactivesolutesinpolyethyleneoxidepolymerfilmsonmicroelectrodes．J．Electroanal．Chem．，1986，208：18522CheG，DongS．StudyonmasstransportinEastman－AQpolymerfilmbyusingnon－steady－statechronoamperometryatanultramicrodiskelectrode．J．Electroanal．Chem．，1993，346：23923DongS，ZhouH．Astudyofthedependenceofferrocenedifusiononelectrolyteconcentrationandsizeinapolymermediumusingnon－steady－statechronoamperometry．J．Electroanal．Chem．，1996，403：11724ZhouH，DongS．Astudyofthedependenceofferrocenediffusiononchainlengthinpolymerelectrolytes．J．Eoectroanal．Chem．，1996，414：12125ZhouH，DongS．Studyonferocenederivativesdifusiondynamicsinpolymerelectrolytebysolid－statevoltammetry．Electrochim．Acta，1996，41（15）：239526丁黎明，董绍俊，汪尔康．高分子固体电解质中分子扩散的微电极固态伏安法研究．第八届全国固态离子学学术会议，长春，1996，特邀报告．27PickupPG，KutnerW，LeidnerCR，MurrayRW．Redoxconductioninsingleandbilayerfilmsofredoxpolymer．J．Am．Chem．Soc．，1984，106：199128JerniganJC，MurrayRW．Electronself－exchangesinanOsmiumpolypyridineredoxpolymerintheab－senceofliquidsolventsbysolid－statevoltammetry．J．Am．Chem．Soc．，1987，109：173829ChidseyCED，MurrayRW．Eleceroactivepolymensandmacromoleculareleceronics．Science，1986，231：2530ChidseyCED，FeldmanBJ，LundgrenC，MurrayRW．Micrometer－spacedplatinuminterdigitatedarrayelectrode：fabrication，theory，andinitialuse．Anal．Chem．，1986，58：60131AbrunaHD，DenisevichP，UmanaM，MeyerTJ，MurrayRW．Rectifyinginterfacesusingtwo－layerfilmsofelectrochemicalypolymerizedvinylpyridineandvinylbipyridinecomplexesofRutheniumandIrononelectrodes．J．Am．Chem．Soc．，1981，103：132DenisevichP，WilmanKW，MurrayRW．Unidirectionalcurrentflowandchargestatetrappingatredoxpolymerinterfacesonbilayerelectrodes：principals，experimentaldemonstration，andtheory．J．Am．Chem．Soc．，1981，103：472733BurgmayerP，MurayRW．Fasteriongatemembranes．J．Electroanal．Chem．，1983，147：33934BurgmayerP，MurayRW．Iongateelectrodes．Polypyrroleasaswitchableionconductormembrane．J．Phys．Chem．，1984，88：251535WatanabeM，LongmireML，MurrayRW．Astudyofferrocenedifusiondynamicsinnetworkpoly（ethyleneoxide）polymerelectrolytebysolid－statevoltammetry．J．Phys．Chem．，1990，94：261436ShoupD，SzaboA．Chronoamperometriccurrentatfinitediskelectrodes．J．Electroanal．Chem．，1982，140：23737BardAJ，FaulknerLR．ElectrochemicalMethods；FundamentalsandApplications．NewYork：JohnWi－ley＆Sons，1980：Chapter938BaranskiAS．Alternatingcurrentvoltammetrywithcarbonfibermicroelectrodes．J．Electrochem．Soc．，1986，133：9339BaranskiAS．Optimizationofacvoltammetricmeasurementsatultramicroelectrodes．J．Electroanal．Chem．，1991，300：30940SmithDE．ElectroanalyticalChemistry．BardAJEd．NewYork：MarcelDekker，1996：Vol．1，Chapter141ReedRA，WoosterTT，MurrayRWetal．Solidstatevoltammetryinionicalyconductingphosphazene－LiCF3SO3films．J．Electrochem．Soc．，1989，136：256542GengL，LongmireML，ReedRAetal．Solid－statevoltammetricmeasurementofplasticizationtransportenhancementinionicalyconductingpoly（ethyleneoxide）films．Chem．Mater．，1989，1：5843WightmanRM．Microvoltammetricelectrodes．Anal．Chem．，1981，53：1125A44SuwandiMS，SternSA．Transportofheavyorganicvaporsthroughsiliconerubber．J．Polym．Sci．，Polym．Phys．Ed．，1973，11：66345ButryDA，AnsonFC．Efectsofelectronexchangeandsingle－filedifusiononchargepropagationinNafionfilmscontainingredoxcouples．J．Am．Chem．Soc．，1983，105：68546DahmsH．Electronicconductioninaqueoussolution．J．Phys．Chem．，1968，72：36247RufI．Experimentalevidenceofelectronicconductioninaqueoussolutions．Electrochim．Acta，1970，15：105948BridgesC，ChadwickAV，WorboysMR．Radiotracerself－difusionmeasurementsinpoly（ethyleneoxide）andpoly（propyleneoxide）electrolytes．Br．Polym．J．，1988，20：20749ZhangH，MurrayRW．Monomerandpolymersolventdynamiccontrolofanelectron－transfercross－reac－tionrateataredoxpolymer／solutioninterface．J．Am．Chem．Soc．，1991，113：518350PinkertonMJ，LeMestY，ZhangHetal．Solid－statevoltammetryandself－difusiondynamicsofalinearmonotaggedredoxpolymer：ω－ferocenecarboxamido－α－methoxypoly（ethyleneoxide）．J．Am．Chem．Soc．，1990，112：373051VelazquezCS，MurrayRW．Synthesisandvoltammetryofatetrathiafulvalenepolymerelectrolytemelt．J．Electroanal．Chem．，1995，396：34952VelazquezCS，HutchisonJE，MurrayRW．Electrochemicalreactionsandchargetransportinundilutedroom－temperaturemeltsofoligo（ethyleneglycol）－basedelectroncarriers．J．Am．Chem．Soc．，1993，115：7896