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Abstract

The stearate nickel L B films is good electroacatlyst for the oxidation of methanol MeOH in alkaline. The electrochemical behaviors of stearate nickel L B films is affected by the concentration of KOH. The rate of quantity of mickel ion and stearic acid in L B films is 1∶1, which means that the nickel ion may exist in -COONi(OH) form. The electrocatalytic process is influenced by the concentration of OH - , it involves the penetration of MeOH into the films. The oxidative currents of MeOH are linearly dependent on the bulk concentration.

Keywords

The stearate nickel L B film, Electrocatalytic oxidation methanol

Publication Date

1997-08-28

Online Available Date

1997-08-28

Revised Date

1997-08-28

Received Date

1997-08-28

References

1张爱强.聚邻氨基酚膜修饰电极的研究:〔学位论文〕.厦门:厦门大学化学系,19922TaraszewskaJ,ReslonekG.Electrocatalyticoxidationofmethanolonaglassycarbonelectrodemodifiedbymickelhydroxideformedbyexsituchemicalprecipitation.J.ofElectroanal.Chem.,1994,364:2093SobkowskiJ,FranaszczukK,DobrowolskaJK.EfectofanionsandpHontheadsorptionandoxidationofmethanolonaplatinumelectrode.J.electroanal.Chem.,1992,330:529

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