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Corresponding Author

Haoqing Wu

Abstract

The discharge mechanism of Li/αSn(HPO4)2 cell has been investigated by means of Xray diffraction, XPS and cyclic voltammetry methodes. It has been shown that the electrochemical intercalation reation exists in the cathode material. There is a new phase after some degree of intercalation. With potential step and galvanostatic techniques, the chemical diffusion cofficients of Li+ in LixSn(HPO4)2 is estimated to be 10-12~10-13 cm2·s-1.

Publication Date

1997-11-28

Online Available Date

1997-11-28

Revised Date

1997-11-28

Received Date

1997-11-28

References

1BernardL,GlaunsingerW.MagneticInvestigationoftheIntercalationcompoundsLixTiS2.SolidStateIonics,1985,17:812PistoiaG.MechanisticstudiesofoxideelectrodesreversiblyincorporatingLi+ions.JournalofPowerSources,1983,9:3073EnriqueRodriguez-castelonetal.IntercalationofPolarOrganicCompoundsintoSn(HOP4)2·H2O.In-org.Chem.,1985,24:11874WestKetal.Determinationofthediferentialcapacityofintercalationelectrodematerialsbyslowpoten-tialscans.ElectrochimicaActa,1983,1(28):975邢雪坤,史美伦,陈民勤,吴浩青.锂在嵌合物LixTiO2中的扩散行为.化学学报,1982,11(40):969

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