Rational Design of Heterostructured Nanomaterials for Accelerating Electrocatalytic Hydrogen Evolution Reaction Kinetics in Alkaline Media

Authors

Hai-Bin Ma, Shanghai Key Laboratory for R&D and Application of Metallic Functional Materials, Institute of New Energy for Vehicles, School of Materials Science and Engineering, Tongji University, Shanghai 201804, China
Xiao-Yan Zhou, Shanghai Key Laboratory for R&D and Application of Metallic Functional Materials, Institute of New Energy for Vehicles, School of Materials Science and Engineering, Tongji University, Shanghai 201804, China
Jia-Yi Li, Shanghai Key Laboratory for R&D and Application of Metallic Functional Materials, Institute of New Energy for Vehicles, School of Materials Science and Engineering, Tongji University, Shanghai 201804, China
Hong-Fei Cheng, Shanghai Key Laboratory for R&D and Application of Metallic Functional Materials, Institute of New Energy for Vehicles, School of Materials Science and Engineering, Tongji University, Shanghai 201804, ChinaFollow
Ji-Wei Ma, Shanghai Key Laboratory for R&D and Application of Metallic Functional Materials, Institute of New Energy for Vehicles, School of Materials Science and Engineering, Tongji University, Shanghai 201804, ChinaFollow

Corresponding Author

Hong-Fei Cheng(cheng_hongfei@tongji.edu.cn);
Ji-Wei Ma (jiwei.ma@tongji.edu.cn)

Abstract

Owing to the merits of high energy density, as well as clean and sustainable properties, hydrogen has been deemed to be a prominent alternative energy to traditional fossil fuels. Electrocatalytic hydrogen evolution reaction (HER) has been considered to be mostly promising for achieving green hydrogen production, and has been widely studied in acidic and alkaline solutions. In particular, HER in alkaline media has high potential to achieve large-scale hydrogen production because of the increased durability of electrode materials. However, for the currently most prominent catalyst Pt, its HER kinetics in an alkaline solution is generally 2–3 orders lower than that occurring in an acidic solution because of the low H+ concentration in alkaline electrolytes. Fortunately, construction of heterostructured electrocatalysts has proved to be an efficient strategy for boosting alkaline HER kinetics because of their various structural merits. The synergistic effect is a unique characteristic of heterostructures, which means that one functional active site serves as a promoter for water dissociation and another one takes a charge of moderate hydrogen adsorption, thus synergistically improving HER performance. In addition, each building block of the heterostructures is tunable, providing more flexibility and chances to construct optimal catalysts. Furthermore, due to the presence of Fermi energy difference between the two components at the interface, the electronic structure of each component could possibly be rationally modulated, thus much enhanced HER performance in alkaline electrolyte can be achieved. With a deeper understanding of on nanoscience and rapid development of nanotechnology, more sophisticated alternative designing strategies have been explored for constructing high-performance heterostructured electrocatalysts. This review presents an outline of the latest development of heterostructured catalysts toward alkaline HER and the rational design principles for constructing interfacial heterostructures to accelerate alkaline HER kinetics. The basic reaction pathways of HER in alkaline media are first described, and then emerging efficient strategies to promote alkaline HER kinetics, including synergistic effect, strain effect, electronic interaction, phase engineering, and architecture engineering. Finally, current existing challenges and research opportunities that deserve further investigation are proposed for the consideration of novel heterostructures towards practical applications.

Graphical Abstract

Keywords

Interfacial heterostructure; Hydrogen production; Water dissociation; Hydrogen adsorption; Synergistic effect

DOI Link

https://doi.org/10.13208/j.electrochem.2305101

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

Publication Date

2024-01-28

Online Available Date

2023-09-09

Revised Date

2023-08-08

Received Date

2023-05-10

Recommended Citation

Hai-Bin Ma, Xiao-Yan Zhou, Jia-Yi Li, Hong-Fei Cheng, Ji-Wei Ma. Rational Design of Heterostructured Nanomaterials for Accelerating Electrocatalytic Hydrogen Evolution Reaction Kinetics in Alkaline Media[J]. Journal of Electrochemistry, 2024 , 30(1): 2305101.
DOI: 10.13208/j.electrochem.2305101
Available at: https://jelectrochem.xmu.edu.cn/journal/vol30/iss1/2