Abstract
Raman, IR, X-ray photoelectron (XPS), and NMR spectra of components in polyacrylonitrilebased electrolytes have been studied. It is found that there are strong interactions among the components though different systems show different interaction characteristics. A concept of competition is proposed between the polymer matrix and the plasticizer on associating with the Li~+ ions. By analyzing the important functions of the plasticizer, a possible mechanism of the ions transport in the polymer electrolyte is suggested.
Publication Date
1998-02-28
Online Available Date
1998-02-28
Revised Date
1998-02-28
Received Date
1998-02-28
Recommended Citation
Zhaoxiang Wang, Biying Huang, Rongjian Xue, Xuejie Huang, Liquan Chen.
Spectroscopic Investigation of Ion Transport Mechanisms in Polyacrylonitrile Based Electrolytes[J]. Journal of Electrochemistry,
1998
,
4(1): Article 16.
DOI: 10.61558/2993-074X.2681
Available at:
https://jelectrochem.xmu.edu.cn/journal/vol4/iss1/16
Included in
Analytical Chemistry Commons, Materials Chemistry Commons, Nanoscience and Nanotechnology Commons, Physical Chemistry Commons
