Study on the Synthesis and Electrochemical Behavior of Poly (Quinonoiddisulfide)

Authors

Xiaohui Tang, Changchun Inst. of Appl. Chem., Chinese Academy of Sciences, Changchun 130022);
Xiuwu Sun, Inst. of Chem., Chin. Academy of Sciences, Beijing 100080);
Yongfang Li, Inst. of Chem., Chin. Academy of Sciences, Beijing 100080);
Shibi Fang, Inst. of Chem., Chin. Academy of Sciences, Beijing 100080);

Corresponding Author

Xiaohui Tang

Abstract

Organic polydisulfide containing quinonoid structure was synthesized by chloromethylation, oxidation by nitric acid, and condensation polymerization with sodium disulfide. The effect of quinonoid structure on the electrochemical behavior of organic polydisulfide was investigated with cyclic voltammetry and chargedischarge measurement. The result shows that quinonoid struture mainly affects the positions of redox peaks of organic polydisulfide, open circuit voltage and discharge platform voltage of cell with the organic polydisulfide as cathode.

DOI Link

https://doi.org/10.61558/2993-074X.2674

Publication Date

1998-02-28

Online Available Date

1998-02-28

Revised Date

1998-02-28

Received Date

1998-02-28

Recommended Citation

Xiaohui Tang, Xiuwu Sun, Yongfang Li, Shibi Fang. Study on the Synthesis and Electrochemical Behavior of Poly (Quinonoiddisulfide)[J]. Journal of Electrochemistry, 1998 , 4(1): Article 9.
DOI: 10.61558/2993-074X.2674
Available at: https://jelectrochem.xmu.edu.cn/journal/vol4/iss1/9

References

1LiuM，ViscoSJ，DeJongheLC．Electrodekineticeoforganodisulfidecathodesforstoragebatteries．J．Electrochem．Soc．，1990，137（3）：750～7592LiuM，ViscoSJ，DeJongheLC．NovelsolidredoxpolymerizationelectrodesAl－solid－statethin－filmrechargeablelithiumbateries．J．Electrochem．Soc．，1991，138（7）：1891～18953LiuM，ViscoSJ，DeJongheLC．NovelsolidredoxpolymerizationelectrodesElectrochemicalproper－ties．J．Electrochem．Soc．，1991，138（7）：1896～19014OyamaN，TatsumaT，SatoTandSotomuraT，Dimercaptan－polyanilinecompositeelectrodesforlithiumbatterieswithhighenergydensity．Nature，1995，373（16）：598～6005BrunerA，USPatent，1．887．396（1932）6WitiakDT，LoperJT，AnanthanS，AlmericoAM，VerhoefVL，FilppiJA．Monoandbis（bioreduc－tive）alkylatingagents：SynthesisandantitumoractivitiesinaB16melanomamodel．J．Medicinal．Chem．，1989，32：1636～16427WoodJH，GibsonRE．Diα－andβ－substitutedaminoethylbenzedes．Ⅰ．2，5－bis－（2－aminoethyl）－hy－droquinones．J．Am．Chem．Soc．，1949，71：393～3948邢其毅．基础有机化学．北京：高等教育出版社，1994：8019YangXQ，XueKH，LeeHS，McbreenJ．x－rayabsorptionstudiesoforganodisulfideredoxpolymericelectrodes．PhysicalReviewB，1992，45（10）：5733～5673610YangXQ，XueKH，LeeHS，GuoYH，McbreenJ．Insitux－rayabsorptionstudiesoforgano－disul－fideredoxpolymericelectrodes．J．Electrochem．Soc．，1993，140（4）：943～946