Abstract
The Deposition mechanism of Lithium on aluminium electrode was studied by using linear sweep voltammetry and potential step method. The formation of α-solid solution was controlled by the diffusion of lithium within the aluminium substance. The formation of β-LiAl alloy was limited by the rate of forming the alloy at the legining, and by diffiusion of lithium through the β- LiAl alloy layer was limited by the rate of forming the alloy at the begining, and by the diffusion of lithium through the β-LiAl alloy later. Neucleation polarization for the formation of β-LiAl alloy was observed. This polarization is an instantaneaus process. There are a Limiting charging patential and a charging current for the LiAl alloy anode.
Publication Date
1998-05-28
Online Available Date
1998-05-28
Revised Date
1998-05-28
Received Date
1998-05-28
Recommended Citation
Shuzhen Duan, Congsheng Guan, Qingrong Shi, Xindong Wang.
Electrode Process of Lithium Ions on Aluminum Electrode in Molten LiCl-KCl[J]. Journal of Electrochemistry,
1998
,
4(2): Article 14.
DOI: 10.61558/2993-074X.2694
Available at:
https://jelectrochem.xmu.edu.cn/journal/vol4/iss2/14
References
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