•  
  •  
 

Corresponding Author

Xinsheng Zhang

Abstract

A packed electrode reactor was used to oxidize to benzoquinone. Anode bed of the reactor has a size of 10~30 mm×450 mm×50 mm(thickness×length×width),and was packed porous lead alloy. A dispersion of benzene in 1 mol/L aqueous sulfuric acid was passed through the reactor. Current efficiency for benzoquinone generation is 62.9% at optimal operating condition: velocity of electrolyte flow, 0.19 ms -1 ;current, 10 A; thickness of anode bed, 10 mm, and percentage of benzene, 24%.

Keywords

electrooxidation, benzene, benzoquinone, packed bed reactor, electrochemical reactor.

Publication Date

1998-08-28

Online Available Date

1998-08-28

Revised Date

1998-08-28

Received Date

1998-08-28

References

1US5075463,US50754622ClarkeJ,EhigamusoeRE,KuhnA.T.etc.Theanodicoxidationofbenzene,tolueneandanisole.J.Electroanal.Chem.InterfacialElectrochem.,1976,70:3333ItoS.,SasakiK.andMurakamiY.etc.Mechanismofformationofmaleicacidbyanodicoxidationofbenzene.DenkiKagaku,1972,40:7334OlmanC.Electrooxidationofbenzeneinafixedbedreactor.JApplElectrochem.1980,10:5535FremeryM,HoverH,SchwarzloseG.Elektrochemischebenzoloxidationeinnebenproduktfreierwegzumhydrochinon.Chem.Ing.Tech.,1974,46(15):6356张新胜,丁平,戴迎春,袁渭康.对苯二醌在固定床反应器内电解制备对苯二酚.华东理工大学学报,1998,24(2):1307陈康宁,金属阳极(第1版).上海:华东师范大学出版社,1989:146~1538OlmanC.Electrosynthesisofpbenzoquinoneandhydroquinone.AIChESymp.Ser.,1981,177(204):2649张新胜.固定床成对电解反应器的基础研究一对苯二酚的电解合成:[博士学位论文].上海华东理工大学,199610StorckA.,EnriquezGranadosM.A.andRogerM.ThebehaviourofporouselectrodesinaflowbyregimeI.theoreticalstudy.ElectrochimicaActa,1982,27(2):293

Share

COinS
 
 

To view the content in your browser, please download Adobe Reader or, alternately,
you may Download the file to your hard drive.

NOTE: The latest versions of Adobe Reader do not support viewing PDF files within Firefox on Mac OS and if you are using a modern (Intel) Mac, there is no official plugin for viewing PDF files within the browser window.