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Abstract

The application of in- situ Raman spect roscopy , particularly surface enhanced Raman spect roscopy (SERS) , in elect rochemist ry is reviewed , including elect rosorption , elect ro2 plating , corrosion , conducting polymers , batteries and nonaqueous media. Recent work on ex2 tending Raman study to t ransition metal surfaces as well as semiconductor surfaces are also out2 lined. The current advance in SERS study and the prospectus are also given.

Keywords

Surface enhanced Raman spectroscopy, electrochemistry, application, prospectus, review

Publication Date

1998-02-28

References

1  田中群, 孙世刚, 罗瑾, 杨勇. 现场光谱电化学研究新进展. 物理化学学报, 1994 ,10 :860

2  Schrotter and H. W. Klochner , in : Weber A. Ed. Raman Spectroscopy of Gases and Liquids.Berlin : Springer-Verlag , 1979 , Vol. 11 : 123

3  Chang R K, Furtak T E Eds. Surface enhanced Raman scattering , New York : Plenum Press , 1982

4  Otto A , Mrozek I , Grabhorn H and Akemann W. Surface-enhanced Raman scattering. J . Phys. Condens. Matter , 1992 , 4 :1 143

5  Moskovits M. Surface-enhanced spectroscopy. Rev. Mod. Phys. ,1985 , 57 : 783

6  Efrima S , Surface-enhanced Raman scattering ( SERS) . in Bockris J O’M , White R E and Conway B E( Eds. ) “, Modern Aspects of Electrochemistry”, New York : Plenum Press , 1985 , 16 :253

7  Fleischmann M , Hill I. Raman spectroscopy , in : Bockris J O’M , White R E and Conway B E , Yeager E“Comprehensive Treatise of Electrochemistry”, New York : Plenum Press , 1985 , 8 : 373

8  Pettinger B , Surface enhanced Raman spectroscopy , in : Lipkowski J , Ross P N. Eds. Adsorption of Moleculesat Metal Electrodes , (VCH , New York , 1992) , p. 285

9  Birke R Land Lombardi J R. Surface enhanced Raman spectroscopy. in Gale R J ( Ed. ) . Spectroelec2trochemistry- theory and practice , New York : Plenum Press , 1988

10  Hembree D M , Oswald J C , Smyre N R. Surface Enhanced Raman Microspectroscopy at Electrode Surfaces. Appl. Spectrosc. , 1987 ,41 : 267

11  Macomber S H , Furtak T E. Surface-enhanced Raman scattering magnified photochemical activation of the sil2ver electrode in aqueous halide electrolytes. Chem. Phys. Lett . , 1982 , 90 : 439·8 · 电  化  学 1999年

12  Gao X P , Gosztola D , Leung LW et al. Surface-enhanced Raman scattering at gold electrodes : Dependence on electrochemical pretreatment conditions and comparisons with silver J . Electroanal. Chem. , 1987 , 233 : 211

13  Pettinger B , Phiopott M R , Gordon J G. Further observation of the surface-enhanced Raman spectrum of wa2ter on silver and copper electrodes. Surf . Sci. , 1981 , 105 : 469

14  Furtak T E , Current understanding of the mechanism of surface-enhanced Raman scattering. J . Electroanal.Chem. , 1983 , 150 : 375

15  Fleischmann M , Graves P R , Robinson J . Enhanced and normal Raman scattering from pyridine adsorbed onrough and smooth silver electrodes. J . Electroanal. Chem. , 1985 , 182 : 73

16  Fleischmann M , Tian Z Q. The effects of the underpotential and overpotential deposition of lead and thalliummon silver on the Raman spectra of adsorbates. J . Electroanal. Chem. , 1987 , 217 : 385

17  Tian Z Q , Li W H , Zou S Z. Potential averaged surface enhanced Raman spectroscopy. Appl. Spectrosc. ,1996 , 50 :1 569

18  Cline M P , Barber P W , Chang R K et al. Surface-enhanced electric intensities on transition- and noble-metalspheroids. J . Opt . Soc. Am. , 1986 , B3 : 15

19  Fleischmann M , Tian Z Q , Li L J . Raman spectroscopy of adsorbates on thin film electrodes deposited on sil2ver substrates. J . Electroanal. Chem. , 1987 , 217 : 397

20  Aramaki K, Uehara J . A SERS study on adsorption of some organic compounds on iron. J . Electrochem.Soc. , 1989 , 136 : 1 299

21  Leung L W , Weaver M J . Extending the metal interface generality of surface-enhanced Raman spectroscopy :Underpotential deposited layers of mercury , thallium , and lead on gold electrodes. J . Electroanal. Chem. , 1987 , 217 : 367

22  Leung L W , Weaver M J . Extending surface-enhanced Raman spectroscopy to transition-metal surfaces : Car2bon monoxide adsorption and electroxidation on platinum- and palladium- coated electrodes. J . Am. Chem.Soc. , 1987 , 109 : 5 113

23  Oblonsky L J , Devine T M , Ager J W. Surface-enhanced Raman scattering from pyridine adsorbed on thinlayers of stainless steel. J . Electrochem. Soc. , 1994 , 141 : 3 312

24  查英华,魏宝明,田中群,林昌健. 表面增强拉曼光谱用于不锈钢缓蚀机理的研究. 腐蚀科学与防护技 术, 1994 , 6 : 58

25  Van Duyne R P , Haushalter J P. Resonance Raman spectroelectrochemistry of semiconductor electrode : The Photooxidation of Tetrathiafulvalene at n- GaAs(100) in Acetonitrile. J . Phys. Chem. , 1984 , 88 : 2 446

26  Feng Q , Cotton T M. A surface-enhanced resonance Raman study of the photoreduction of methylviologen on a P- InP semiconductor electrode. J . Phys. Chem. , 1986 , 90 : 983

27  Zou S Z , Willians C T , Chen E K- Yet al. Probing molecular vibrations at catalytically significant interfaces : A new ubiquity of surface-enhanced Raman scattering. J . Am. Chem. Soc. , 1998 , 120 : 3 811

28  Krasser W , Renouprez A J . Enhanced Raman spectroscopy of Coadsorbed Carbon Monoxide and Hydrogen on Small Nickel Particles. J . Raman Spectrosc. , 1981 , 11 : 425

29  Bilmes A. , Rubim J C , Otto A et al. SERS from pyridine adsorbed on electrodispersed platinum electrodes.Chem. Phys. Lett . , 1989 , 159 : 89

30  Pettinger B , Friedrich A , Tiedemann U. Raman spectroscopy at metal electrodes. J . Electroanal. Chem. ,1990 , 280 : 49

31  Fleischmann M , Sockalingum D , Musiani M M. The use of infrared Fourier Transform techniques in the study 第 1 期          田中群等:电化学原位拉曼光谱的应用及进展 ·9 ·of surface enhanced spectra. Spectrochim. Acta , 1990 , 46A : 285

32  Huang Q J , Yao J L , Mao B W et al. Surface Raman spectroscopic studies of pyrazine adsorbed onto nickel electrodes. Chem. Phys. Lett . , 1997 , 271 : 101

33  Tian Z Q , Gao J S , Li X Q et al. Can Raman spectroscopy become a general technique for surface science and electrochemistry. J . Raman Spectrosc. , 1998 , 29 :703

34  Ren B , Huang Q J , Cai W B et al. Surface Raman spectra of pyridine and hydrogen adsorbed at Pt and Ni electrodes. J . Electroanal. Chem. . 1996 , 415 : 175

35  Gao J S , Tian Z Q. Surface Raman spectroscopic studies of ruthenium , rhodium and palladium electrodes de2 posited on glassy carbon substrates. Spectrochimica Acta A , 1997 , 53 : 1 595

36  Tian Z Q , Ren B , Mao B W. Extending surface Raman spectroscopy to transition metal surfaces for practical applications I. Vibrational properties of thiocyanate and carbon monoxide adsorbed on electrochemically activat2ed platinum surfaces. J . Phys. Chem. , 1997 , 101 :1 338

37  Cai W B , Ren B , Liu F M et al. Investigation of surface-enhanced Raman scattering from platinum electrodes using a confocal Raman microscope : dependence of surface roughening pretreatment . Surf . Sci. , 1998 , 406 :9

38  Ren B , Liu F M , Xie J et al. In- situ monitoring of Raman scattering and photoilluminanscence from silicon surfaces in HF solutions. Appl. Phys. Lett . , 1998 , 72 : 933

39  Tian Z Q , Ren B , Chen Y X et al. Probing electrode/ electrolyte interfacial structures in the potential region of hydrogen evolution by Raman spectroscopy. J . Chem. Soc. Faraday Trans. , 1996 , 20 : 3 829

40  Ren B , Yao J L , Li X Q et al. Applications of confocal Raman microscopy in electrochemistry. In : Heyns AM , The XVIth International Conference on Raman Spectroscopy , New York : John Wiley & Sons Ltd. , 1998 : 808

41  Brolo A G, Odziemkowski M and Irish D E. An in situ Raman spectroscopic study of electrochemical processes in mercury- solution interphases. J . Raman Spectrosc. , 1998 , 29 :713

42  Cooney R P , Reid E S , Fleischmann M. Thiocyanate adsorption and corrosion at silver electrodes : A Raman spectroscopic study. J . Chem. Soc. , Faraday Trans. , 1977 , 73 : 1 691

43  Wetzel H , Gerischer H , Pettinger B. Surface-enhanced Raman scattering from silver-cyanide and silver- thiocy2nate vibrations and the importance of adatoms. Chem. Phys. Lett . , 1981 , 80 : 159

44  Weaver M J , Barz F , Gordon J G. Surface-enhanced Raman spectroscopy of electrochemically characterized in2 terfaces : potential dependence of Raman spectra for thiocyanate at silver electrodes. Surf . Sci. , 1983 , 125 :409

45  Gao X P , Weaver M J . Metal-adsorbate vibrational frequencies as a probe of surface bonding : halide and pseu2 dohalide at gold electrodes. J . Phys. Chem. , 1986 : 90 : 4 057

46  Tian Z Q , Li W H , Qiao Z H. Molecular-level investigations of different types of coadsorption at Ag electrodes by Raman spectroscopy. Russian. J . Electrochem. , 1995 , 31 : 1 014.

47  Sharonov S , Nabiev I , Feofanov A et al. Confocal 3- dimensional scanning laser Raman- SERS-fluorescence mi2 croprobe spectral imaging and high- resolution applications. J . Raman Spectrosc. , 1994 , 25 : 699

48  田中群. 表面增强拉曼光谱研究电化学中的共吸附现象. 物理化学学报,1988 , 4 :344

49  Chen T T , Chang R K. Surface-enhanced Raman scattering of interfacial DOD , HOD , and OD- . Surf . Sci. ,1985 , 158 : 325

50  Tian Z Q , Sligalaev S K, Zou S Z et al. The observation of SERS of water in a widepotential range from theAg/ NaClO4 system. Electrochim. Acta , 1994 , 39 : 2 195 ·10 · 电  化  学 1999年

51  Chen Y X , Zou S Z , Huang K Q et al. SERS studies of electrode/ electrolyte interfacial water II. librations ofwater correlated to hydrogen evolution reaction. J . Raman Spectrosc. , 1998 , 29 : 749

52  Gosztola D , Weaver M J . Electroinduced structural changes in manganese dioxide + manganese hydroxide filmsas characterized by real- time surface-enhanced Raman spectroscopy. J . Electroanal. Chem. , 1989 , 271 : 141

53  Casado J , Otero T F , Hotta S , et al , Electrochemical doping in a series of alpha ,alpha‘- dimethyl end-capped oligothienyls —An FT-Raman confirmation of a radical cation generation. Opt . Mater. , 1998 , 9 : 82

54  Martin F , Prieto A C , De Saja J A et al. SERS study of the pyrrole polymerization. J . Mol. Struct . , 1988 ,174 : 363

55  田中群,雷良才,景遐斌. 苯胺在银和金电极上的表面增强拉曼光谱. 物理化学学报, 1988 , 4 : 458

56  钟传健,田中群,田昭武. 吡咯电化学聚合的现场ESR 波谱和Raman 光谱研究. 中国科学B , 1989 , 12 : 1 259

57  陈衍珍,辜志俊,田中群. 导电聚合物单体的光电聚合. 物理化学学报. 1993 , 9 (2) : 277

58  Bukowska J , Jackowska K. In situ Raman studies of polypyrrole formation on a silver electrode. Electrochim.Acta , 1990 , 35(2) : 315

59  Fujita W , Teramae N , Haraguchi H. Formation of thiophene oligomers and polythiophene on a roughened goldelectrode studied by surface enhanced Raman scattering. Chem. Lett . , 1994 , 511

60  Fujita W , Ishioka T , Teramae N. Polymerization of pyrrole on a roughened gold electrode studied by surface enhanced Raman scattering. Chem. Lett . , 1994 , 933

61  Wu L L , Luo J , Lin Z H. Spectroelectrochemical studies of poly-o-phenylenediamine. Part I. In situ resonanceRaman spectroscopy. J . Electroanal. Chem. , 1996 , 417 : 53

62  Probst M , Holze R. Spectroelectrochemical investigation of polyxylidines. Ber. Bensenges Phys. Chem. ,1996 , 100 : 1 286

63  Bazzaoui E A , Levi G, Aeiyach S et al. SERS spectra of polythiophere in doped and undoped states. J . Phys.Chem. , 1995 , 99 : 6 628

64  Malinauskas A , Bron M , Holze R. Electrochemical and Raman spectroscopic studies of electrosynthesizedcopolymers and bilayer structures of polyaniline and poly (o-phenylenediamine) . Sythet . Metal. , 1998 , 92 :127

65  Fleischmann M , Sundholm G, Tian Z. Q. An SERS Study of Silver Electrodeposition from Thiourea and Cyanide Containing Solutions. Electrochim. Acta , 1986 , 31 : 907

66  Daujotis V and Kairys V. The mechanism of electroreduction of silver cyanide complexes in aqueous elec2trolytes- II. Interpretation of SERS data. Electrochim. Acta , 1998 , 42 :1 345

67  Reents B , Pleith W , Macagno V A and Lacconi G I. Influence of thiourea on silver deposition : Spectroscopicinvestigation. J . Electroanal. Chem. , 1998 , 453 :121

68  牛振江,姚士冰,周绍民. 现场表面拉曼光谱研究Fe-Mo 合金诱导共沉积. 物理化学学报, 1998 , 14 :1074

69  Fleischmann M , Hill I R , Mengoli Get al. A comparative study of the efficiency of some organic inhibitors forthe corrosion of copper on aqueous chloride media using electrochemical and surface-enhanced Raman scattering techniques. Electrochim. Acta , 1985 , 30 : 879

70  徐海波, 余家康, 董俊华. 硫脲和尿素在银电极上吸附行为的电化学和SERS 研究. 腐蚀科学与防护技术, 1997 , 9 :302

71  Thierry D , Leygraf C. Simultaneous Raman spectroscopy and electrochemical studies of corrosion inhibiting 第 1 期          田中群等:电化学原位拉曼光谱的应用及进展 ·11 ·molecules on copper. J . Electrochem. Soc. , 1985 , 132 : 1 009

72  Musiani M M , Mengoli G. An Electrochemical and SERS Investigation of the Influence of pH on the Effec2tiveness of some Corrosion Inhibitors of Copper. J . Electroanal. Chem. , 1987 , 217 :187

73  林仲华,王逢春,田中群. 2-氨基嘧啶对铜的缓蚀机理. 物理化学学报, 1992 , 8 : 87

74  Hamilton J C , Farmer J , Anderson R J . In situ Raman spectroscopy of anodic films formed on copper and sil2ver in sodium hydroxide solution. J . Electrochem. Soc. , 1986 , 133 : 739

75  Huang W W , Frech P. In situ Raman studies of graphite surface structures during lithium electrochemical in2tercalation. J . Electrochem. Soc. , 1998 , 145 : 765

76  钟发平,杨汉西,徐知三,查全性. 微型拉曼电解池现场研究硫酰氯的电化学还原. 物理化学学报,1992 ,8 :266

77  Ostrovskii D , Torell L M. Appetecchi G B et al. An electrochemical and Raman spectroscopical study of gelpolymer electrolytes for lithium batteries. Solid State Ionics , 1998 , 106 :19

78  Lo YL , Hwang B J . In situ Raman studies on cathodically deposited nickel hydroxide films and electroless Ni-P electrodes in 1 M KOH solution. Langmuir , 1998 , 14 : 944

79  顾仁敖,曹佩根,孙如,曹文东,徐浩元. 非水体系表面增强拉曼光谱研究. 光散射学报,1998 , 10 :177

80  顾仁敖, 宗亚平, 冷永章. 非水体系中哌啶在银电极表面的表面增强喇曼散射. 光学学报,1989 , 9 :1 041

81  Hill I R , Irish D E and Atkinson G F. Investigations of Silver Electrode Surface in Propylene Carbonate/ Alkali Halide Electrolytes by Surface Enhanced Raman Scattering. Langmuir , 1986 , 2 :752

82  Xiao YJ , Wang T , Wang X Q , Gao X X. Surface-enhanced near-infrared Raman spectroscopy of nicotinamide adenine dinucleotides on a gold electrode. J . Electroanal. Chem. , 1997 , 433 : 49

83  Bryant M A , Pemberton J E. Surface Raman scattering of self-assembled monolayers formed from 1-alkanethi2ols at Ag. J . Am. Chem. Soc. , 1991 , 113 : 3 629

84  Zhu T , Yu H Z , Cai S M et al. Electrochemical in- situ Raman study of azobenzene self-assembled monolayers on gold. Cryst . Liq. Cryst . Sci. Tec. A , 1997 , 29 479

85  Hatchett D W , Stevenson KJ , Lacy W B et al. Electrochemical oxidative adsorption of ethanethiolate on Ag(111) . J . Am. Chem. Soc. , 1997 , 119 : 6 596

86  Tsen M , Sun L. Surface-enhanced Raman scattering from functionalized self-assembled monolayers. 1. Dis2tance dependence of enhanced Raman scattering from a terminal phenyl group. Anal. Chim. Acta , 1995 , 307 :333

87  Patterson M L , Weaver M J . Surface enhanced Raman spectroscopy as a probe of adsorbate- surface bonding :Simple alkenes and alkynes adsorbed at gold electrodes. J . Phys. Chem. , 1985 , 89 : 5 046

88  Smith B D , Irish D E , Kedzierzawski P et al. A SERS study of the intermediate and poisoning species formedduring the electrochemical reduction of CO2 on Copper. J . Electrochem. Soc. , 1997 , 144 : 4 288

89  Bryant M A , Joa S L and Pemberton J E. Raman scattering from monolayer Films of thiophenol and 4-mercap2topyridine at Pt surfaces. Langmuir , 1992 , 8 :753

90  Bryant S P and Furtak T E. Surface plasmon assisted Raman scattering from electrochemically controlled adsor2bates on flat single crystal silver. Electrochim. Acta , 1991 , 11/ 12 :1 879

91  Brolo A G, Irish D E , Lipkowski J . Surface-enhanced Raman spectra of pyridine and pyrazine adsorbed on aAu ( 210) single-crystal electrode. FT-Raman Microscopy : Discussion and Preliminary Results. J . Phys.Chem. , 1997 , 101 :3 906·12 · 电  化  学 1999年

92  Bruckbauer A and Otto A. Raman spectroscopy of pyridine adsorbed on single crystal copper electrodes. J . Ra2man. Spectrosc. , 1998 , 29 :665

93  Futamata M , Highly- sensitive Raman spectroscopy using surface-plasmon-polariton. In : Heyns A M , TheXVIth International Conference on Raman Spectroscopy , New York : John Wiley & Sons Ltd. , 1998 , 356

94  Futamata M. High- sensitive Raman spectroscopy to characterize adsorbates on the electrode. Surf . Sci. ,1997 , 386 :89

95  Li W H , Tian Z Q , Gao J S , et al. In- situ time- resolved Raman spectroscopic studies of silver electrode inNaSCN solution. Chin. Chem. Lett . , 1993 , 4 :829

96  Shi C T , Zhang W , Birke R L et al. SERS investigation of the adsorption and electroreduction of 4-cyanopyri2dine on a silver electrode. J . Electroanal. Chem. , 1997 , 423 : 67

97  Messerschmidt R G and Chase D B. FT-Raman Microscopy : Discussion and Preliminary Results. Appl. Spec2trosc. , 1989 , 43 :11

98  Yang X M , Tryk DA , Hashimoto K et al. Examination of the photoreaction of p- nitrobenzoic acid on electro2chemically roughened silver using surface-enhanced Raman imaging (SERI) . J . Phys. Chem. B. , 1998 , 102 :4 933.

99  Yang X M , Tryk D A , Hashimoto K et al. Surface-enhanced Raman imaging (SERI) as a technique for imag2ing molecular monolayers with chemical selectivity under ambient conditions. J . Raman. Spectrosc. , 1998 ,29 :725.

100  Ozeki T and Irish D E. The application of concentration- distance profiling Raman microspectroscopy to thestudy of the photoinduced crystallization of triethylenediamine triiodide upon a silver electrode. J . Phys.Chem. , 1992 , 96 :1 306

101  张树霖. 突破分辨率极限的拉曼光谱学—简介近场光学与近场拉曼光谱. 光散射学报, 1997 , 9 : 47

102  李五湖, 田中群. 光导纤维拉曼光谱技术及其在化学中的应用. 光散射学报,1993 , 5 :50

103  Huy N Q , Jouan M and Dao N Q. Use of a mono- Fiber optrode in remote and in situ measurements by theRaman/ laser/ fiber optics (RL FO) method. Appl. Spectrosc. , 1993 , 47 :2 013

104  Tian Z Q , Li W H , Ren B. Simultaneous STM and Raman measurements on electrochemical interfaces. J .Electroanal. Chem. , 1996 , 401 :247

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