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Corresponding Author

Sifu Hu

Abstract

Properties of self_passivation for the anodic passive film of 1Cr18Ni9Ti and the firsthand passive film of SUS 36 stainless steel in vinylon aldehyde solution(H 2SO 4(240 g/L)+Na 2SO 4(70 g/L)+HCHO(25 g/L)+[Fe 3+ ](35.4 mg/L)+[Cl -](240 mg/L) at 70 ℃ were studied by galvanostatic and potentiostatic polarization mesurements. The effects of compponents of vinylon aldehyde solution, i.e. Fe 3+ and Cl -, on the passivation behaviours of stainless steel have also been investigated. The experimental results showed there is a conversion zone of the active/passive state if the area ratio of active/passive state on these stainless steel attained to a critical value, while the locally damaged passive film by mechinery process could be repassivated by polarization of active_passive couple in a certain medium and so that corrosion may be prevented.

Keywords

Galvanic method, Passive film of stainless steel, Vinylon aldehyde solution, Self_passivation

Publication Date

1999-08-28

Online Available Date

1999-08-28

Revised Date

1999-08-28

Received Date

1999-08-28

References

1  吴 剑.不锈 钢的腐蚀 破坏与防 蚀技术 .腐蚀与 防护,1998(19)1 :4 1 2   Hashim oto K , Asa m ik et al . Corrsion Science ,1 997 ,19(3) :3 3  小 若正伦. 袁宝林译 .金属的 腐蚀破坏 与防蚀 技术 北京 :化学工 业出版社 ,199 8 .8 4  许 川壁等. S U S3 6 不锈钢 在醛化液 中的腐蚀 行为的 研究福 建化工,1983 ,4 :1

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