Studies of the Electrode Preparation of Electrode from Lead Carbonate for Lead acid Battery Ⅰ The activation of the PME

Authors

Zhongxu Dai
Dihua Wang
Junwei Jiang
Yunhong Zhou
Jinyun Zou

Corresponding Author

Jinyun Zou

Abstract

Lead carbonate which was an intermediate product in lead hydrometallurgy without pollution of lead vapor and sulfur dioxide was selected as electrode material of lead_acid batteries. In the present work,the performances of PbO 2/PbSO 4 or PbSO 4/Pb electrode transformed from PbCO 3 have been investigated by powder microelectrode technique combined with cyclic voltammetry.The results show that the CV characteristics of either negative or positive electrode prepared from PbCO 3 is as good as that of both electrodes made from lead oxide produced by mill machine,when a powder microelectrode with PbCO 3 transformed into PbSO 4 in 1.0 mol/L H 2SO 4 solution,and then activated to form Pb or PbO 2 using an unsymmetrical interchangeable signal( Q a/ Q c or Q c/ Q a being 0.2～0.4) in 2.0～2.5 mol/L H 2SO 4 solution.Furthermore,comparing the negative electrode activated in 2.5 mol/L H 2SO 4 solution containing 4% carbon colloid with one activated in the same H 2SO 4 solution concentration without ABC,the cyclic voltammetric characteristics of the former has been obviously improved.It is possible that the carbon colloid particles can be adsorbed on PbSO 4 crystals,which could increase the conductivity and reduce the shrinking of the electrode

Keywords

Lead carbonate, Lead_acid battery, Powder microelectrode, Activation

DOI Link

https://doi.org/10.61558/2993-074X.3202

Publication Date

1999-11-28

Online Available Date

1999-11-28

Revised Date

1999-11-28

Received Date

1999-11-28

Recommended Citation

Zhongxu Dai, Dihua Wang, Junwei Jiang, Yunhong Zhou, Jinyun Zou. Studies of the Electrode Preparation of Electrode from Lead Carbonate for Lead acid Battery Ⅰ The activation of the PME[J]. Journal of Electrochemistry, 1999 , 5(4): Article 14.
DOI: 10.61558/2993-074X.3202
Available at: https://jelectrochem.xmu.edu.cn/journal/vol5/iss4/14

References

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