Abstract
A cathodic indirect electro_oxidation system was established for indirect electro_oxidize dimethyl sulfoxide to dimethyl sulfone with electro_reduction generated H 2O 2 catalyzed by the pertungstate/tungstate(WO 5 2- /WO 4 2- )redox mediator. Influences of current density,pH,temperature,and the current efficiencies etc. on the cathodic indirect electro_oxidation of dimethyl sulfone were investigated for determining optimum reaction conditions.The current efficiency reached more than 70%.Mother_liquid could be recycled to use without pollution.
Publication Date
2000-02-28
Online Available Date
2000-02-28
Revised Date
2000-02-28
Received Date
2000-02-28
Recommended Citation
Deng-ping GU, Rui-zhi WANG, Hong-kun ZHANG, Xue-ying ZHANG, Wei LI.
Cathodic Indirect Electro-Oxidation——Organic Electro-Synthesis Dimethyl Sulfone[J]. Journal of Electrochemistry,
2000
,
6(1): Article 15.
DOI: 10.61558/2993-074X.3213
Available at:
https://jelectrochem.xmu.edu.cn/journal/vol6/iss1/15
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