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Abstract

An investigation has been made to obtain the glyoxalic acid by the electrochemical oxidation of glyoxal solution with hydrochloric acid under various experimental conditions.The cell used consists of a lead cathode, a DSA anode and a cation_exchange membrane of model CM001.The current efficiency and yield for glyoxalic acid generation were 80.0% and 91.1% respectively, under optimal operating conditions: velocity of electrolyte flow 1.4 m·s -1 ,current density 450A·m -2 ,temperature 30~40 ℃,initial concentration of glyoxal and hydrochloric acid 9.1%~16.0%, 4%~6%, respectively.

Publication Date

2000-02-28

Online Available Date

2000-02-28

Revised Date

2000-02-28

Received Date

2000-02-28

References

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[5 ] WuMing_dong .Studyonelectrochemicalsynthesisofglyoxylicacid [D].EastChinaUniversityofScienceandTechology ,China ,1998.

[6 ] HouYu ,HeHui_xin ,TongYu_ting,GuDeng_ping.TheElectrochemicalsynthesisofglyoxglicacidinapairedelectrodes[J].Chemicalworld(HuaxueShijie) ,1992 ,1:38.

[7] USPatent 4,2 35 ,6 84,Nov .2 5 ,1980 .

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