Abstract
New developments in the areas of molten salt systems, molten salt batteries and power, electrodeposition of metals and alloys, electro synthesis of compound materials in molten salts are presented. Application of molten electrochemistry to the energy supply and consumption,global environment, resources and recycling are predicted.
Keywords
Molten salt systems, Batteries and power, Electrodeposition of metals and alloys, Electro synthesis of compound materials, Protection of environment
Publication Date
2001-02-28
Online Available Date
2001-02-28
Revised Date
2001-02-28
Received Date
2001-02-28
Recommended Citation
Qi-qin YANG, Shu zhen DUAN.
The New Developments of Molten Salt Electrochemistry[J]. Journal of Electrochemistry,
2001
,
7(1): Article 14.
DOI: 10.61558/2993-074X.3234
Available at:
https://jelectrochem.xmu.edu.cn/journal/vol7/iss1/14
References
[1] Ito .Y .Abrightfutureformoltensaltsinscienceandtechnology[J].DenkiKagaku ,1999,6 7(6 ) :52 8
[2 ] Hussey .CL .Roomtemperaturemoltensalts:Abrightfutureofapplicationsincleantechnology[J].DenkiKagaku ,1999,6 7(6 ) :52 7
[3] YangQi_qin ,FangBei_long .Ambienttemperaturemoltensalts[J].HuaxueTongbao(inChinese) ,1993,(5) :14.
[4 ] DuanZhu_zhen ,QiaoZhi_yu .MoltenSaltChemistry—PrincipleandApplication[M ](inChinese) .Beijing :TheMetallurgicalIndustryPress ,1990 .
[5] CarmichaelAJ ,HardacreC ,HolberyJD .Structureandbondinginionicliquids[C].ExtendedAbstractsofthe 196thMeetingoftheElectrochemicalSociety ,Inc .Hawaii,U .S .A .,Oct .17 2 2 ,1999.No .2 2 59.
[6 ] MatsumotoH ,YanagidaM ,Tanimotoetal.Improvementofionicconductivityofroomtemperaturemoltensaltbasedonquaternaryammoniumcationandimideanion[C].ibid ,No .2 2 56 .
[7] NewmanDS ,ChenDY ,SilkowskiC .ThedensityandHNMRspectraofbinarysolutionsofN methylpyridinumiodideandN methylpyridiniumchloride[C].ibid ,No .2 2 55.
[8] CalderiaMOSP ,SequeriaCAC .Electrochemicalstudiesonlowtemperatureamidemelts[R].MoltenSaltForum .Trans.Tech .Publications,Switzerland ,1993/ 94 ,1- 2 :4 0 7.
[9] YangQi_qin .Applicationofmoltensalttechnology[J].UniversityChemistry (inChinese) ,1994 ,9(3) :1.
[10 ] YangQiqin ,ZhuDelong ,LiuGuankun ,etal.Applicationofurea NaBr KBrmelttoelectrodepositionofmetalsandalloys[C].ExtendedAbstractsofThe 193rdMeetingofTheElectrochemicalSociety ,Inc .SanDiego ,U .S .A ,May 3 8,1998.No .10 85.
[11] BelhommeC ,CassirM ,TessierC ,etal.LithiumdepthprofileonNiOmoltencarbonatefuelcellcathodebynuclearmicroprobe[J].Electrochem .andSolidLetters ,2 0 0 0 ,3(5) :2 16 .
[12 ] DuanShuzhen ,FangBaizeng ,ShiQingrong ,etal.AstudyofsurfacemodificationofMCFCelectrode[C].ExtendedAbstractsofThe 193rdMeetingofTheElectrochemicalSociety ,Inc .SanDiego ,U .S .A .,May3 8,1998.No .10 85
[13] SmithDS ,WinnickJ.Cesium containingelectrolyteforthemoltencarbonatefuelcell[J].Electrochem .andSolidLetters ,2 0 0 0 ,2 (5) :2 0 7.
[14] YoshikawaM ,MugikurY ,WatanabeT ,etal.TheBehaviorofMCFCsusingLi/KandLi/Nacarbonatesastheelectrolyteathighpressure[J].J .Electrochem .Soc.,1999,146 (8) :2 834.
[15] KouraN ,IizukaK ,IdemotoY ,etal.LiandLi Alnegativeelectrodecharacteristicsforthelithiumsec ondarybattery[J].DenkiKagaku .1999,6 7(6 ) :70 6 .
[16 ] FungYS ,ZhouR .SpinelLiMn2 O4 electrodeinroomtemperaturemoltensalt[J].ibid .1999,6 7(6 ) :713.
[17] KatayamaYKonishiikeI ,MiuraT ,etal.ElectrochemicalbehaviorofvanadiumtrichlorideinMEICmoltensalt.ibid .1999,6 7(6 ) :547.
[18] YamamotoH ,KawakamiA ,KurodaK ,etal.FormationofMg Nihydrogenabsorptionalloyfilmbymoltensaltselectrolysis[J].ibid .1999,6 7(6 ) :6 55.
[19] ItoY .Selectedtopicsofmoltensaltelectrochemistry[C].ExtendedAbstractsofThe 196thMeetingofTheElectrochemicalSociety ,Inc .Hawaii,U .S .A .,Oct.17 2 2 ,1999,No .2 2 88.
[2 0 ] ItoY ,NohiraT .HydrogenelectrodereactioninamoltenLiCl KCl LiHsystem[C].ExtendedAbstractsofThe 193rdMeetingofTheElectrochemicalSociety ,Inc .SanDiego ,U .S .A .,May 3 8,1998.No10 71.
[2 1] GuanCongzheng ,DuanShuzhen ,ZhaoGuangwen ,etal.Effectofyttriumonlithium aluminumelectrode[C].RareMetals .1995,14(4 ) :2 53.
[2 2 ] GuanCong_shen ,DuanShu_zhen .Effectsofceriumonthelithium_aluminumelectrode[J].J .ChineseRareEarthSoc .(inChinese) ,1996 ,14(3) :2 15.
[2 3] HenriksenG ,KaunT ,JansenA ,etal.AdvancedcelltechnologyforhighperformanceLi Al/FeS2 sec ondarybatteries[C].ExtendedAbstractsofThe 193rdMeetingofTheElectrochemicalSociety ,Inc .SanDiego ,U .S .A .,May 3 8,1998.No .10 6 5.
[2 4 ] PrakashJ .DevelopmentofahighpowerZebraBattery[C].ExtendedAbstractsofThe 196thMeetingofTheElectrochemicalSociety ,Inc .Hawaii,U .S .A .,Oct.17 2 2 ,1999.No .2 330 .
[2 5] IshiharaA ,FujimoriT ,MotohiroM ,etal.Hightemperatureelectrochemicalheatpump[C].ibid .No .2 333.
[2 6 ] GrjotheimK ,KvandeH ,QiuZhuxian .KeyimprovementstoHall H啨roultsincetheendofWorldWar 1[J].J.Metals ,1995,Nov .32 .
[2 7] QiuZhuxian .Moltensaltinalumiumelectrolysisatlowtemperaturesof 80 0 90 0℃ [C].ExtendedAb stractsofThe 193rdMeetingofTheElectrochemicalSociety ,Inc.SanDiego ,U .S .A .,May 3 8,1998,No .10 80 .
[2 8] NumataH .Electrodepositionofrefractorymetalsinmoltensalts[J].J .Surf.Finish .Soc.Jap .,1998,4 9(4 ) :341.
[2 9] KoyamaK ,MorishitaM ,UmezuT .SmoothelectrodepositionoftungstenformKF B2 O3 WO3.moltensalt[J].DenkiKagaku ,1999,6 7(6 ) :6 77.
[30 ] DickG B .ElectrodepositionofTainhightemperaturemelts[J].Galvanotechnik 1997,88(12 ) :3982 .
[31] TakasawaY ,OnoueT ,HoshinoY ,etal.Improvementofcurrentefficiencyinelectrowinniguraniummetalinmoltenfluorides[J].DenkiKagaku .1999,6 7(6 ) :718.
[32 ] TeramaeN ,TakasawaY ,OnoueT ,etal.Demonstrationexperimentoncontinuousuraniummetalproduc tionsystembymoltensaltelectrolysis[C].ExtendedAbstractsofThe 193rdMeetingofTheElectrochemi calSociety ,Inc .SanDiego ,U .S .A .,May 3 8,1998,No .10 51.
[33] KouraN .Electrodepositionofmetalsandalloysfrommoltensaltelectrolytes[J].J .Surf.Finish .Soc .Jap .(inJapanese) ,1995,4 6 (12 ) :10 88.
[34] SaffordGR ,Jovic’VD ,ZhuQ ,etal.TheelectrodepositionofAl Cualloysfromroom temperaturechloroaluminateelectrolytes[C].ExtendedAbstractsofThe 196thMeetingofTheElectrochemicalSociety ,Inc .Hawaii,U .S .A .,Oct .17 2 2 ,1999.No .2 2 93.
[35] LinMeichen ,ChenPoyu ,SunIwen .ElectrodepositionofCu ZnalloysfromalewisacidicZinc MEICmoltensalt[C].ibid .No .2 2 90 .
[36 ] KouraN ,UmebayashiT ,IdemotoY ,etal.ElectrodepositionofNb SnalloyfromSnCl2 NbCl5 MEICmoltensalts[J].DenkiKagaku ,1999,6 7(6 ) :6 84 .
[37] HaarbergGM ,StaffordG .Electrochenicalbehaviourofdissolvedniobium ,molybdenumandtantalumspeciesinmoltenchloroaluminates[C].ExtendedAbstractsofThe 196thMeetingofTheElectrochemicalSociety ,Inc .Hawaii,U .S .A .,Oct .17 2 2 ,1999.No .2 2 95.
[38] StewartG ,HusseyCL .Electrodepositionoftransitionmetal aluminumalloysfrommoltenAlCl3 NaCl[C].ExtendedAbstractsofThe 193thMeetingofTheElectrochemicalSociety ,Inc .SanDiego ,U .S .A .,May3 8,1998,No .10 37.
[39] YangQi_qin .Studiesonelectrodepositionofrareearthmetalsandtheiralloysinmoltensalts[J].Electro chemistry(inChinese) .1997,3(2 ) :12 2 .
[4 0 ] ZhouChun_gen ,DuanShu_zhen .TheelectrodeprocessofY(Ⅲ )oncopperelectrodeanditssurfacemetal lizing[J].Electrochemistry (inChinese) .1995,1(1) :93.
[4 1] KawakamiM ,TakenakaT ,NagaoK .Electrodereactionsofboridesofrefractorymetalsinfluoroboratemelt[C].ExtendedAbstractsofThe 196thMeetingofTheElectrochemicalSociety ,Inc .Hawaii,U .S .A .,Oct .17 2 2 ,1999.No .2 318.
[4 2 ] DuanShu_zhen ,ShiQing_rong ,WangXin_dong ,etal.Cathodeprocessintheelectrolyticcodepositionofti taniumborideinthemoltenfluoride[J].BeijingKejiDaxueXuebao ,1996 ,18(1) :4 .
[4 3] MakarovaOV ,PolyakovEG .Theeffectofthemeltcompositiononelecttodeprocessesandstructureoftantalum boridecoatings[C].ExtendedAbstractsofthe 196thMeetingoftheElectrochemicalSociety ,No .2 32 0 .
[4 4] KuznetsovSA ,KuznetesovaSV .Depositionofniobiumdiboridecaotingbyhigh temperatureelectrochemi calsynthesisfromchloro fluoridemetls[C].ExtendedAbstractsofThe 193thMeetingofTheElectrochemi calSociety ,Inc .SanDiego ,U .S .A .,May 3 8,1998,No .10 4 8.
[4 5] GotoT .ItoY .Formationofnitridethinfilmsbyelectrochemicalimplantation[C].ExtendedAbstractsofThe 196thMeetingofTheElectrochemicalSociety ,Inc.Hawaii,U .S .A .,Oct.17 2 2 ,1999.No .2 32 1.
[4 6 ] TasakaA ,MakinoT ,SuzukiY ,etal.ElectrolyticproductionofnotrogentrifluordewithanickelbasedcompositeelectrodepreparedHIP[C].ibid .No .2 332 .
[4 7] NohiraT ,ItoY .ElectrodebehaviorofSiandevolutionofSiH4 inmoltenLiCl KCl LiHsystems[C].DenkiKagaku ,1999,6 7(6 ) :6 35.