•  
  •  
 

Corresponding Author

YANG

Abstract

Some recent research work about applications of confocal Raman micro spectroscopy for study of practical electrode materials carried out in our lab has been briefly introduced. The examples include study of electrochemical Li + intercalation process, characterization of surface oxide film on AB 5 type electrodes and passive film and pitting corrosion of Rebar electrodes.

Keywords

Li + intercalation electrodes, spinel LiMn 2O 4 electrodes, AB 5 type metal hydride electrodes, surface oxide film, pitting corrosion, Rebar eletrodes, confocal Raman spectroscopy

Publication Date

2001-02-28

Online Available Date

2001-02-28

Revised Date

2001-02-28

Received Date

2001-02-28

References

[1] ChuW .Structure ,performanceandcharacterizationofmanganesenodule ,LiMn2 O4 andothercathodemate rialsforlithiumionbatteries[D]..XiamenUniversity ,1999.

[2 ] ChuW ,ZhangZR ,LiuZT ,YangY ,LinZG .In_situandex_situRamanspectroscopiccharacterizationofLi+ _intercalationprocessesandstructuralchangesofspinelormodifiedspinelmaterials[C],in“MicroPowerSources”editedZaghibKandSurampudiS ,PV2 0 0 0_3,TheElectrochemicalSocietyInc,12 5.

[3] NanJM EffectsofsurfacepppretreatmentonsurfacepropertiesandperformancesofAB5_typehydrogenstoragealloyelectrodeforMH/NiBattery[D].XiamenUniversity ,1998.

[4 ] NanJM ,YangY ,YouJK ,LiXQ ,LinZG .In_situandex_situcharacterizationofsurfaceoxidefilmsonAB5 typemetal_hydrideelectrodes[J].J.AlloysandCompounds ,1999,2 93- 2 95:74 7.

[5] ChenXG .TheComposition ,structureandin_situspectroscopiccharacterizationofpassivefilmsoniron_basedelectrodes[D].XiamenUniversity ,1997:b)ChenXG ,YangY ,LinZG .In_situspectroscopicandscan ningprobemicroscopiccharacterizationofpassivefilmsoniron_basedelectrodes,inproceedingofsymposiumon“passivityandbreakdown” ,TheElectrochemicalSocietyInc[C].1997:180~ 184

[6 ] AmmundsenBA ,BurnsGR ,RoziereJ,etal.Latticedynamicsandvibrationalspectraoflithiummanganeseoxide :Acomputersimulationandspectroscopicstudy[J].J .Phys .Chem .B .1999,10 3:5175

[7] HuangW ,FrechR .In_situRamanspectroscopicstudiessofelectrochemicalintercalationinLixMn2 O4 _basedcathodes[J].J .PowerSources ,1999:81~ 82 .

[8] J .F .Jackovitz .ProceedingsoftheSymposiumontheNickelElectrode[C].editedbyR .G .Gunther,S .Gross .TheElectrochem .Soc .Inc .,Pennington ,NJ ,PV82~ 4 ,4 8~ 6 8.

[9] CornilsenC ,KarjalaPJ,LoysellePL .Structuralcomparisonofnickelelectrodesandprecursorphases[J].J .PowerSources ,1990 ,2 2 :351andreferencetherein .

[10 ] MelendresCA ,PadenW ,TaniB ,WalczakW .Onthestructureofthehigheroxideformsofnickel[J].J .Electrochem .Soc .,1987,134:76 2 .

[11] MelendresCA ,PankuchM .OnthecompositionofthepassivefilmonNickel:asurface_enhancedRamanspectroelectrochemicalstudy[J].J.Electroanal..Chem .,1992 ,333:10 3.

[12 ] MaslarJE ,HurstWS ,BowersWJ ,etal.In_situRamanspectroscopicinvestigationofaqueousironcorro sionatelevatedtemperaturesandpressures[J].J .Electrochem .Soc.,2 0 0 0 ,147:2 532 .

[13] OdziemkowskiM ,FlisJ ,IrishDE .RamanspectralandelectrochemicalstudiesofsurfacefilmformationonironanditsalloyswithcarboninNa2 CO3/NaHCO3solutionwithreferencetostresscorrosioncracking[J].Electrochim .Acta ,1994 ,39:2 2 2 5.

[14] Hugot LeGoffA ,FlisJ,BoucheritN ,JoiretS ,WilinskiJ .UseofRamanspectroscopyandrotatingsplitringdiskelectrodeforidentificationofsurfacelayersonIronin 1MKOH [J].J .Electrochem .Soc .,1990 ,137:2 6 84 .

[15] ThierryD ,PerssonO ,LeygrafC ,BoucheritN ,Hugot_LeGoffA .RamanspectroscopyandXPSinvestiga tionofanodiccorrosionfilmsformedonFe_Moalloysinalkalinesolutions[J].Corros.Sci.,1991,32 :2 73.

Share

COinS
 
 

To view the content in your browser, please download Adobe Reader or, alternately,
you may Download the file to your hard drive.

NOTE: The latest versions of Adobe Reader do not support viewing PDF files within Firefox on Mac OS and if you are using a modern (Intel) Mac, there is no official plugin for viewing PDF files within the browser window.