Abstract
Lithium nickel oxide as the positive electrode of lithium ion batteries has aroused more and more interests.This paper reviews the recent reserches on synthesis and element_substitution of LiNiO 2 cathode material,and summarizes the intrinsical relationship between properties and sturcture of the material.The developments of new synthesis methods and mutil_substitution of the material are expecting to be studied in the future research.
Keywords
Lithium nickel oxide, Synthesis, Structure, Performance, Multi_element_substitution
Publication Date
2001-05-28
Online Available Date
2001-05-28
Revised Date
2001-05-28
Received Date
2001-05-28
Recommended Citation
Han-san LIU, Yong YANG, Zhong-ru ZHANG, Zu-geng LIN.
New progress in studies of lithium nickel oxide as positive electrode materials of lithium ion batteris[J]. Journal of Electrochemistry,
2001
,
7(2): Article 7.
DOI: 10.61558/2993-074X.3245
Available at:
https://jelectrochem.xmu.edu.cn/journal/vol7/iss2/7
References
[1] EudoM ,KimC ,NishimuraK .RecentdevelopmentofcarbonmaterialsforLiionbatteries[J] .Carbon ,2 0 0 0 ,38( 2 ) :183～ 197.
[2 ] WinterM ,BesenhardJO ,BesenhardO ,etal.Insertionelectrodematerialsforrechargeablelithiumbatteries[J] .Adv .Mater.,1998,10 :74 2 .
[3] PoizotP ,LaruelleS ,GrugeonS ,etal.Nano_sizedtransition_metaloxidesasnegativeelectrodematerialsforlithiumionionbatteries[J] .Nature ,2 0 0 0 ,4 0 7:4 96～ 4 99.
[4 ] BooneB .Owens .SolidStateelectrolytes :overviewofmaterialsandapplicationsduringthelastthirdoftheTwemtiethCentury[J] .J .PowerSources,2 0 0 0 ,90 :2～ 8.
[5] BrunoScrosati.Recentadvancesinlithiumionbatterymaterials[J] .Electrochemica .Acta ,2 0 0 0 ,4 5:2 4 6 1～2 4 6 6 .
[6 ] BrousselyM .RecentdevelopmentsonlithiumionbatteriesatSAFT [J] .J .PowerSources ,1999,81_82 :14 0～14 3.
[7] TamuraK ,HoribaT .Large_scaledevelopmentoflithiumbatteriesforelectricvehiclesandelectricpowerstor ageapplications[J] .J.PowerSources ,1999,81_82 :156～ 16 1.
[8] LuChung_hsin ,Lee_Cheng .Reactionmechanismandkineticsanalysisoflithiumnickeloxideduringsolid_statereaction[J] .J .Mater.Chem ,2 0 0 0 ,10 :14 0 3.
[9 ] BarbouxP ,TarasconJM ,ShokoohiF .K .TheuseofacetatesasprecursorsforthelowtemperaturesynthesisofLiNiO2 andLiCoO2 intercalationcompounds[J] .J.SolidStateChem .,1991,94 :185.
[10 ] SchoonmanJ ,TullerHL ,KelderEM .Defectchemicalaspectsoflithium_ionbatterycathodes[J] .J.PowerSources ,1999,81_82 :4 4～ 4 8.
[11] KannoR ,KuboHKawamotoY ,etal.PhaserelationshipandlithiumdeintercalationinlithiumnickeloxidesJ] .J .SolidStateChem .,1994 ,10 :2 16 .
[12 ] LiW ,CurrieJC ,WolstenholmeJ.InfuenceofmorphologyonthestabilityofLiNiO2 [J] .J .powerSources,1997,6 8( 2 ) :56 5～ 56 9.
[13] ChangCC ,KumtaPN .Particulatesol_gelsynthesisandelectrochemicalcharacterizationofLiMO2 (M =Ni,Ni0 .75 Co0 .2 5 )powders[J] .JournalofPowerSources,1998,75( 1) :4 4～ 55.
[14 ] SpahrME ,NovakP ,SchnyderB ,etal.Characterizationoflayeredlithiumnikelmanganeseoxidessynthe sizedbyanoveloxidativecoprecipitationmethodandtheirelectrochemicalperformanceaslithiuminsertionelectrodematerials[J] .JournaloftheelectrochemicalSociety ,1998,14 5( 4 ) :1113～ 112 1.
[15] LuCH ,LeeWC .Novelemulisionprocessforsynthesiaingsubmicronlithiumnickeloxidepowderusedinlithiumionbatteries[J] .MaterialsLetters,1999,4 0 ( 3) :10 3～ 10 8.
[16 ] LeeYS ,SunYK ,NahmKS .SynthesisandcharacterizationofLiNiO2 cathodematerialpreparedbyanadiphicacid_assistedsol_gelmethodforlithiumsecondarybatteries[J] .SolidStateIonics ,1999,118( 1_2 ) 159～ 16 8.
[17] JulienC ,LetranchantC ,RonganS ,etal.LayeredLiNi0 .5 Co0 .5 O2 cathodematerialsfrownbysoft_chemistrybiavarionsmethod[J] .MaterialsScienceandEngineering ,2 0 0 0 ,B76 :14 5～ 155.
[18] JulienC ,MichaelSS ,ZielkieniczS .StructrualandelectrochemicalpropertiesofLiNi0 .3 Co0 .7O2 synthesizedbydifferentlow_temperatruetechniques[J] .InernationalJournalofInorganicMaterials ,1999,:2 9～ 37.
[19] PalacinMR ,LarcherD ,AudemerA ,etal .Low_temperatruesynthesisofLiNiO2 _Reactionmechanism ,sta bility ,andelectrochemicalproperties[J] .JournaloftheElectrochemicalsociety ,1997,14 4 ( 12 ) :4 2 2 6～ 4 2 36
[2 0 ] YamadaK ,SatoN ,FujinoT ,etal.PreparationofLiNiO2 andLiMyMi1_yO2 (M =Co ,Al)filmsbyelectrostat icspraydeposition[J] .JournalofSolidStateelectrochemistry ,1999,3( 3) :14 8～ 153.
[2 1] MarutaJ ,YasudaH ,YamachM .Low_temperaturesynthesisoflithiumnickelatepositivematerialfromnickelhydroxideforlithiumcells[J] .J .Powersources ,2 0 0 0 ,90 :89～ 94
[2 2 ] ObrovacMN ,MaoO ,DahnJR .StructureandelectrochemistryofLiMO2 (M =ti,Mn ,Fe,Co ,Ni) preparedbymechanchemicalsynthesis [J] .SolidStateIonics,1998,112 :9～ 19.
[2 3] ObrovacMN ,MaoO ,DahnJR .StructureandelectrochemistryofLiMO2 (M =Ti,Mn ,Fe,Co ,Ni)preparedbymechanochemicalsynthesis[J] .SolidStateIonics ,1998,112 :9～ 19.
[2 4 ] OhzukuT ,VedaA ,NagayamaM .ElectrochemistryandstructuralchmistryofLiNiO2 (R3m)for 4Voltsec ondarylithiumcells[J] .J .Electrochem .Soc .,1996 ,14 0 ( 7) :186 2～ 186 9.
[2 5] BrousselyM ,BiensanP ,SimonB .Lithiuminsertionintohostmateials :thekeytosuccessforLiionbatteries[J] .ElectrochimicaActa ,1999,4 5:7.
[2 6 ] PeresJP ,DelmasC ,RougierA ,etal.Therelationshipbetweenthecompositionoflithiumnickeloxideandthelossofreversivilityduringthefirstcycle[J] .J.Phys.Chem .Solids ,1996 ,57( 6～ 8) :10 57～ 10 6 0 .
[2 7] RougierA ,GravereauP ,DelmasC .OptimizationofthemcompositionoftheLi1 -zNi1 +zO2 electrodemateri als :tructural,maganetic ,andecectrochemicalstdies [J] .J .Electrochem .Soc .,1996 ,14 3( 3) :116 8～ 1175.
[2 8] DelmasC ,PeresJP ,RougierA ,etal.OnthebehavioroftheLixMiO2 system :anelectrochemicalandstruc turaloverview [J] .J .PowerSources ,1997,6 8:12 1～ 12 5.
[2 9] LeeKyung_Keun ,KimKwang_Bum .ElectrochemicalandstructuralcharacterizationofLiNi1 -yCoyO2 ( 0
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