•  
  •  
 

Abstract

The characteristics of organic electrolyte solutions and its influences on the ion conductivity are summarized. The chemistry and electrochemistry of organic electrolyte solutions and characteristics of ordinary organic solvents are introduced. Progresses in studies of organic electrolyte solutions such as electrolyte salts, organic solvents, additives in recent years are reviewed, current situation of the studies of organic electrolyte solutions were also discussed.

Keywords

Li ion batteries, Organic electrolyte solutions, Electrolyte salts, Conductivity additives

Publication Date

2001-11-28

Online Available Date

2001-11-28

Revised Date

2001-11-28

Received Date

2001-11-28

References

[1] XuZhong yu,ZhengHong he.Researchprogressoncompatibilityofelectrolytewithcarbonnegativeelectrodeinlithiumionbatterise[J].ChineseJournalofPowerSources,2000,24(5):295~301.

[2] MakotoUe,ShoichiroMori.Mobilityandionicassociationoflithiumsaltsinapropylenecarbonate ethy1methy1carbonatemixedsolvent[J].J.Electrochem.Soc.,1995,142(8)2577~2581.

[3] WangJiqiang.Technicaladvance,applicationsandmarketprospectsoflithiumionrechargeablebatteries[J].ChineseJournalofPowerSources,1996,20(4):147~151.

[4] AbrahamKM .Directionsinlithiumbatteryresearchanddevelopment[J].ElectrochimiActa.1993.38(9),1233~1248.

[5] GeorgeE .Blomgren.Electrolytesforadvanedbatteries[J].JournalofPowerSources,1999,8182:112~118.

[6] DahnJR ,VonSackenU ,JuzkowMW ,etal.RechargeableLiNO2/carboncells[J].J.Electrochem.Soc.,1991,138(8):2207~2211.

[7] ShoichiroMori,HitoshiAsahina,HitoshiSuzuki,etal.Chemicalpropertiesofvariousorganicelectrolytesforlithiumrechargeablebatteries1.Characterizationofpassivatinglayerformedongraphiteinalkylcabonateso lution[J].JournalofPowerSources,1997,68:59~64.

[8] XuZhong yu,ZhengHong he.Researchprogressoncompatibilityofelectrolytewithcarbonnegativeelectrodeinlithiumionbatteries[J].ChineseJournalofSources,2000,24(3):171~177.

[9] AurbachD ,MarkovskyB ,LeviMD ,etal.Newinsightsintotheinteractionsbetweenelectrodematerialsandelectrolytesolutionsforadvancednonaqueousbatteries[J].JournalofPowerSources,1999,8182:95~111.

[10] DoronAurbach,YairEinEli,BorisMarkovsky,etal.ThestudyofelectrolytesolutionsbasedonEthleneanddiethylcarbonatesforrechargeableLibatteries[J].J.Electrochem.Soc.,1995,142(9):2882~2890.

[11] AurbachD ,DorouxML ,FaguyPW ,etal.Identificationofsurfacefilmsformedonlithiuminpropylenecarbonatesolutions[J].J .Electrochem.Soc.,1987,134(7):1611~1620.

[12] FelixJoho,PetrNovak.SNIFTIRinvestigationoftheoxidativedecompositionoforganic carbonate basedelectrolytesforlithium ioncells[J].ElectrochimicaActa,2000,45:3589~3599.

[13] DoronAurbach,ArieZaban,YosefGofer,etal.Recentstudiesofthelithium liquidelectrolyteinterfaceelectrochemical,morphologicalandspectralstudiesofafewimportantsystems[J].JournalofPowerSources,1995,54:76~84.

[14] TheveninJG ,MullerRH .Impedanceoflithiumelectrodeinaprogylenecarbonateelectrolyte.J .Elec trochem.Soc.,1987,134:273~280.

[15] WuShenghui,YouJinkua,LinZugeeng.Studyoncarbonnegativeelectrodeforlithiumionbatteries[J].ChineseJournalofPowerSources,1998,22(1):35~39.

[16] DengZhao yang,ZhouZhi cai,PengZhong dong,etal.Investigationofheat treatedpetroleumcokesasnegativeelectrodeforlithiumionbatteries[J].ChineseJournalofPowerSources,2000,34(3):135~138.

[17] YoshidaH ,FukunagaT ,HazamaT ,etal.Degradationmehanismofalkylcarbonatesolventsusedinlithi um ioncellsduringinitialcharging[J].JournalofPowerSources,1997,68:311~315.

[18] TobishimaSI ,HayashiK ,NemotoY ,etal.Influenceofthecompositionofternarymixedsolventelec trolytesonpropertiesofrechargeablelithiumcells[J].JournalofAppliedElectrochemistry,1997,27:902~907.

[19] CapigliaC ,SaitoY ,KageyamaH ,etal.17Liand19Fdiffusioncoefficientsandthermalpropertiesofnon aqueouselectrolytesolutionsforrechargeablelithiumbatteries[J].JournalofPowerSouces,1999,8182:859~892.

[20] GuyomardD ,TarasconJM .HighvoltagestableliquidelectrolytesforLi1+xMn2O4/carbonrocking chairlithiumbatteries[J].JournalofpowerSouces,1995,54:92~98.

[21] YukioSasaki,MamoruHosoya,MinoruHanda.Lithiumcyclingeffciencyofternarysolventelectrolyteswithethylenecarbonate dimethylcarbonatemixture[J].JournalofPowerSources.1997,68:492~496.

[22] TobishimaS ,ArakawaM ,HiraiT ,etal.USPatent:4737424,1988.

[23] TobishimaS ,KatsuyaHayashi,SaitoK ,etal.Ethylenecarbonateternarymixedsolventeletrolytesofrechargeablelithiumbatteries[J].ElectrochimicaActa,1995,40(5):537~544.

[24] FusajiKita,AkiraKawakami,JinNie,etal.Onthecharacteristicsofelectrolyteswithnewlithiumimidesalts[J].JournalofPowerSources,2000,68:307~310.

[25] WangHsienMing,YasakawaHideki,etal.Electrolytesforsecondarylithiumbatteriesandthebatteries[P].JPNo.200040524.Feb.8,2000.

[26] Holcomb,NelsonR ,PaulGNixon,etal.SynthesisofLiCH (SO2CF3)2 andIonicconductiovityofployether saltcomplexes[J].Electrochem.Soc.,1996,143(4):1297~1300.

[27] GaoFeng,BarkerJeremy,LiuPeikang.Thermallystable,highlyconductivesalt[P]USPat.No.6015639,Jan.18,2000.

[28] SasakiSachio,YamaguchiHiroyuki.Organiclithiumphosphate,itsmanufacture,andlow non aqueuselec trolyteandsecondarynon aqueouselectrolytelithiumbatteryusingit[P].JPNo.99335382,Dec.7,1999.

[29] TobishimaShinichi,HayashiKatsuya,YamkiJunichi.Lithiumsecondarybatterieswithnon aqueouselec trolytes[P].JPNo.0750174,Feb.21,1995.

[30] YokoyamaKeiichi,SasanoTakako,HiwaraAkio.Fluorine substitutedcycliccarbonateelectrolyticsolutionsandbatterycontainingthesame[P].USPat.No.6010806,Jan.4,2000.

[31] YokoyamaKeiichi,HiwaraAkio.FujitaAkio,etal.Carbonatecompounds,non aqueouselectroyticsolutionsandbatteriescomprisingnon aqueouselectrolyticsolutions[P].US .Pat.No.5847188,Dec.8,1998.

[32] Ein lliy,ThomasSR ,KochVR ,etal.NewelectrolyteforLi ionbattary[J].J .Electrochem.Soc.,1996,143:L195~197.

[33] UrbarchD ,EinEliY ,ChusidO .ThecorrelationbetweenthesurfacechemistryandtheperformanceofLi/cabonintercalationanodesforrechargeable“rocking chair”typebatteries[J].J .Electrochem.Soc.,1994,141:603~610.

[34] ShuZhiX ,McmillanRoderickS ,MurrayJohnJ .Electrolyteforasecondarycell[P]USPat.No.5529859.June25,1996.

[35] NajiA ,GhanbajaJ ,WillmannP ,etal.Newhalogenateadditivestopopylenecarbonate basedelectrolytesforlithium ionbatteries[J].ElectrochimicaActa,2000,45:1839~1899.

[36] HerlemG ,FahysB .N Butylamineassolventforlithiumsaltelectrolytes,structureandpropertiesofconcen tratedsolutions[J].ElectrochimActa,1996,41:2753~2759.

[37] HoriuchiHiroshi,TsutsumiMasami,WatanabeIsao,etal.Nonaqueouselectrolyteforlithiumsecondarybattery[P].JPNo.10064584A .19980306.

[38] ShuZX ,McmillanRS ,MurrayJJ ,etal.Effectsof12crown4ontheelectrochemicalintercalationoflithi umintographite[J].J .Appl.Electrochem.,1996,41:2753~2759.

[39] AurbachD ,WeissmanI ,ZabanA ,etal.OntheroleofwatercontaminationinrechargeableLibatteries[J].ElectrochimicaActa,1999,45:1135~1140.

[40] StuxArnoldM ,BarkerTeremy.Additivesforinhibitingdecompositionoflithiumsaltsandelectrolytescon tainingsaidadditives[P].USPat.No.5707760,Jan.13,1998

Share

COinS
 
 

To view the content in your browser, please download Adobe Reader or, alternately,
you may Download the file to your hard drive.

NOTE: The latest versions of Adobe Reader do not support viewing PDF files within Firefox on Mac OS and if you are using a modern (Intel) Mac, there is no official plugin for viewing PDF files within the browser window.