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Abstract

Enhanced photocurrent in dye_sensitized photoelectrochemical cell was obtained by post_treating the TiO 2 nanoporous film electrode with TiCl 4. By investigating the effect of the post_treatment on surface area, pore size distribution, laser pulse induced current transient of the film electrode, photocurrent increase by the post_treatment was assigned to the improved electron percolation resulting from broadening of interparticle neck.

Publication Date

2002-02-28

Online Available Date

2002-02-28

Revised Date

2002-02-28

Received Date

2002-02-28

References

[1] O′ReganB ,Gr tzelM .Alow_cost,high_efficiencysolarcellbasedondye_sensitizedcol loidalTiO2 films[J].Nature,1991,353,737.

[2] HaoY ,YangM ,YuC ,etal.Photoelectrochemicalstudiesonacid_dopedpolyanilineassensitizerforTiO2 nanoporousfilm[J].Sol.EnergyMater.Sol.Cells,1998,56:75.

[3] NazeerudinMK ,KayA ,RodicioI,etal.Conversionoflighttoelectricitybycis_X2Bis(2,2’_bipyridyl_4,4’_dicarboxylate)ruthenium(Ⅱ)charge_transfersensitizers(X =Cl-,Br-,I-,CN-,andSCN-)onnanocrystallineTiO2 electrodes[J].J.Am.Chem.Soc.,1993,115:6382.

[4] RenY ,ZhangZ ,GaoE ,etal.Adye_sensitizednanoporousTiO2 photoelectrochemicalcellwithnovelgelnetworkpolymerelectrolyte[J].J .Appl.Electrochem.,2001,31:445.

[5] RenY ,ZhangZ ,FangS ,etal.ApplicationofPEObasedgelnetworkpolymerelec trolytesindye_sensitizedphotoelectrochemicalcells[J].Sol.EnergyMater.Sol.Cells,2002,71:253.

[6] LeeS ,JunY ,KimKJ ,etal.Modificationofelectrodesinnanocrystallinedye_sensitizedTiO2 solarcells[J].Sol.EnergyMater.Sol.Cells.2001,65:193

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