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Corresponding Author

Jian-qing ZHANG(zjq@zju.edu.cn)

Abstract

Al-substituted α-Ni(OH)2 was prepared by a complexation-precipitation method and characterized by XRD.The electrochemical performance was tested by the charge-discharge method. The experimental results of orthogonal test showed that the effect order of some key preparative conditions on the electrochemical performance of Al-substituted α-Ni(OH)2 was the concentration of aqueous ammonia, the content of aluminum and pH value.The optimum prepareative conditions for obtaining the sample with maximum specific discharge capacity (304 mAh·g-1) were 0.5 mol·L-1 aqueous ammonia, 15 mol% Al content and pH 11.0.

Keywords

Al-substituted α-Ni(OH)2, Complexation-precipitation, Orthogonal test

Publication Date

2002-02-28

Online Available Date

2002-02-28

Revised Date

2001-09-27

Received Date

2001-06-25

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