Abstract
The performance of a direct ethanol fuel cell based on Nafion115 was reported.PtRu/C and Pt/C were used as ethanol anode and oxygen cathode catalysts in a single cell of size 9 cm 2 .The effects of temperature,oxygen pressure,the flow rate of ethanol, and oxygen, and ethanol concentration were tentatively studied.The experimental results showed that the cell open circuit voltage 0.608 V,the cell voltage 0.329 V at 50 mA/cm 2 ,and the peak power density 19.25 mW/cm 2 were reached under the conditions of T cell =85 ℃, P O2 =0.5 MPa, C ethanol =1.0 mol/L and with the flow rate of ethanol and oxygen being 0.5 mL/min and 68 mL/min separately.
Keywords
Direct ethanol fuel cell (DEFC), Membrane electrode assembly (MEA), Nafion membrane, Cell performance.
Publication Date
2002-02-28
Online Available Date
2002-02-28
Revised Date
2002-02-28
Received Date
2002-02-28
Recommended Citation
Shu-qin SONG, Li-kang CHEN, Jian-guo LIU, Zhao-bin WEI, Qin XIN.
Preliminary Study on Direct Ethanol Fuel Cell[J]. Journal of Electrochemistry,
2002
,
8(1): Article 18.
DOI: 10.61558/2993-074X.3284
Available at:
https://jelectrochem.xmu.edu.cn/journal/vol8/iss1/18
References
[1] SurampudiS ,NarayananSR ,VamosE ,etal.Advancesindirectoxidationmethanolfuelcells[J].J .PowerSoruces,1994,47:377.
[2] HampsonNA ,WilarsMJ .Themethanol_airfuelcell:aselectivereviewofmethanoloxidationmechanismsatplatinumelectrodesinacidelectrolytes[J].J.PowerSources,1979,4:191.
[3] HeinzelA ,BarraganVM .Areviewofthestate_of_the_artofthemethanolcrossoverindirectmethanolfuelcells[J].J .PowerSources,1999,84:70.
[4] LalandeG ,FaubertG ,CoteR ,etal.Catalyticactivityandstabilityofheat treatedironphthalocyaninesfortheelectroreductinofoxygeninpolymerelectrolytefuelcells[J].J .PowerSources,1996,61:227.
[5] ScottK ,TaamaWM ,KramerS ,etal.Limitingcurrentbehaviorofthedirectmethanolfuelcell[J].Elec trochim.Acta,1999,45:945.
[6] IwasitaT ,RaschB ,CattanelE ,etal.Asniftirsstudyofethanoloxidationonplatinum[J].Electrochim.Acta,1989,34:1073.
[7] DelimeF ,LegerJM ,LamyC .OptimizationofplatinumdispersioninPtPEMelectrodes:applicationtotheelectrooxidationofethanol[J].J .Appl.Electrochem.,1998,28:27
[8] BltowskaBrzezinskaM ,LuczakT .Electrocatalyticoxidationofmono andpolyhydricalcoholsongoldandplat inum[J].J.Appl.Electrochem.,1997,27:999.
[9] EedenB ,MorinM C ,HahnF ,etal.Insituanalysisbyinfraredreflectancespectroscopyoftheadsorbedspeciesresultingfromtheelectrosorptionofethanolonplatinuminacidmedium[J].J.Electroanal.Chem.,1987,229:353.
[10] JosePISouza,FranciscoJ,BotelhoRabelo,etal.Performanceofaco electrodepositedPtRuelectrodefortheelectro oxidationofethanolstudiedbyinsituFTIRspectroscopy[J].J.Electroanal.Chem.,1997,420:17.
[11] HitmiH ,BelgsirEM ,LegerJ_M ,etal.Akineticanalysisoftheelectro oxidationofethanolataplatinumelectrodeinacidmedium[J].Electrochim.Acta,1994,39:407.
[12] JiangtaoWang,WasmusS ,SavinellRF .Evaluationofethanol,1 propanol,and2 propanolinadirectoxida tionpolymer electrodefuelcell[J].J .Electrochem.Soc.,1995,142:4218.
[13] TremiliosiFilhoG ,GonzalezER ,MotheoAJ ,etal.Electro oxidationofethanolongold:analysisofthereac tionproductsandmechanism[J].J .Electroanal.Chem.,1998,444:31.
[14] TheophilosIoannides.Thermodynamicanalysisofethanolprocessorsforfuelcellapplications[J].J .PowerSources,2001,92:17.
[15] TheophilosIoannides,StylianosNeophytides.Efficiencyofasolidpolymerfuelcelloperationonethnaol[J].J .PowerSources,2000,91:150.
[16] ScottK ,TaamaWM ,ArgyropoulousP .Engineeringaspectsofthedirectmethanolfuelcellsystem[J].J .PowerSources,1999,79:43.
[17] RenX ,WilsonMS ,gottesteldS .Highperformancedirectmethnaolpolymerelectrolytefuelcells[J].J .Elec trochem.Soc.1996,143:L12
Included in
Catalysis and Reaction Engineering Commons, Engineering Science and Materials Commons, Materials Chemistry Commons, Materials Science and Engineering Commons, Physical Chemistry Commons, Power and Energy Commons