•  
  •  
 

Corresponding Author

Sheng_liang ZHAO

Abstract

We present a reviewed the development and status of electrolyte for LiC 6/electrolyte/cathode battery. The effect of the salt, solvent, additive and impurity on the conductivity of the electrolyte, formation of the solid_electrolyte_interphase (SEI) and cycle life of the battery were described.

Keywords

electrolyte, lithium_ion Battery, SEI, conductivity

Publication Date

2002-05-28

Online Available Date

2002-05-28

Revised Date

2002-05-28

Received Date

2002-05-28

References

[1] D .FauteuxandR .koksbangmRechargeablelithiumbatteryanodes:alternativestometalliclithium[J].JournalofPowerSources,1993,23.

[2] HeiderU ,OestenR ,JungnitzM .Challengeinmanufacturingelectrolytesolutionsforlithiumandlithiumionbatteriesqualitycontrolandminimizingcontaminationlevel[J].J .PowerSources,1999:81~82,119.

[3] RitchieAG .Recentdevelopmentsandfutureprospectsforlithiumrechargeablebatteries[J].J.powersources,2001,96:1~4.

[4] PlichtaEJ ,BehlWK .Alow_temperatureelectrolyteforlithiumandlithium_ionbatteries[J].J .PowerSources,2000,88:192.

[5] YukioSasaki,NamoruHosoya,MinoruHanda.Lithiumcyclingefficiencyofternarysolventelectrolyteswithethylenecarbonate_dimethylcarbonatemixture[J].J.powersources,1997,68:492

[6] HerreyreS ,HuchetO ,BarusseayS .NewLiionelectrolytesforLowtemperatureapplications[C].In:Pro ceedingsofthe10thinternationalmeetingonlithiumbatteries,Lithium2000.Como,May2000,Abstractno,282.

[7] MoritaM ,IshikawaM ,MatsudaY .Organicelectrolytesforrechargeablelithiumionbatteries[M ].In:M .Wakihara,O .Yamamoto(Eds.),LithiumIonBatteries,Kodansha,Tokyo:Wiley/VCH ,Weiheim,1998.156.

[8] QiyiXing.BasalOrganicChemistry[M ].Beijing:AdvancedEducationPress,2000.6.

[9] McbreenJ,LeeHS ,YangXQ ,SunX .Newapproachestothedesignofpolymerandliquidelectrolytesforlithiumbatteries[J].J .PowerSources,2000,89:163.

[10] ChusidO ,GoferY ,AurbachD ,etal.StudiesoftheinterfacebetweenlithiumelectrodesandpolymericelectrolytesystemsusinginsituFTIRspectroscopy[J].JournalofPowerSources,2001,97~98:632.

[11] AurbachD ,Ein_EliY ,ChusidO .ThecorrelationbetweenthesurfacechemistryandtheperformanceofLi_carbonintercalationanodesforrechargeable”rockingchair”typebatteries[J].J .Electrochemistry.Soc,1994,141:603.

[12] PeledE .InlithiumBatteries[M ](EditedbyJ .P .Gaobano)chap.3.NewYork:AcademicPress,1993.

[13] Yamaki,Jun_ichi,Tobishima,Shin_ichi,etal.Aconsiderationofthemorphologyofelectrochemicallyde positedlithiuminanorganicelectrolyte[J]..JournalofPowerSources,1998,74:219.

[14] DeyAN ,SullivanBP .Theelectrochemicaldecompositionofpropylenecarbonateongraphite[J].J.Elec trochem.Soc.,1970,117:222.

[15] SaitoK ,ArakawaM ,TobishimaS ,YamakiJ .Specificsurface_areameasurementoflithiumanodeinrechargeablelithiumcells[J].JournalofPowerSources,1998,72:111.

[16] NajiA ,GhanbajaJ,WillmannP .ThereareseveralmethodsreportedtoimprovethebatteryperformancewithPCbasedelectrolyte[J].Carbon,1997,35:845.

[17] NajiA ,GhanbajaJ ,WillmannP ,BillaudD .Newhalogenatedadditivestopropylenecarbonatebasedelec trolytesforlithium_ionbatteries[J].ElectrochimcaActa,2000,45:1893~1899.

[18] YEin_Eli,SRThomas.NewelectrolytesystemforLi_ionbattery[J].J ..Electrochem.Soc.,1996,143:L195.

[19] NajiA ,GhanbajaJ ,WillmannP ,BillaudD .Newhalogenatedadditivestopropylenecarbonatebasedelec trolytesforlithium_ionbatteries[J].ElectrochimcaActa,2000,45:1893.

[20] ChungGeun_Chang,KimHyung_jin.OriginofGraphiteExfoliation:AnInvestigationoftheImportantRoleofSolventCointercalation[J].J .electrochemicalSociety,2000,147(12):4391.

[21] ChungGeun_Chang,JinKimHyeong,JunSongHui.Newcycliccarbonatesolventforlithiumionbatteries:trans_2,3_butylenecarbonate[J].Electrochem.Comm,1999,1:493~496.

[22] YairEin_Eli,BorisMarkovsky,DoronAurbach.ThedependenceoftheperformanceofLi_CintercalationanodesforLi_ionsecondarybatteriesontheelectrolytesolutioncomposition[J].ElectrochimcaActa,1990,39(17):2559.

[23] AurbachD ,MarkowskyB ,SchechterA ,Ein_EliY .AcomparativestudyofsyntheticgraphiteandLielec trodesonelectrolytesolutionsbasedonethylenecarbonate_dimethylcarbonatemixtures[J].J.Electrochem.Soc.,1996,143:3809..

[24] HeiderU ,OestenR ,JungnitzM .Challengeinmanufacturingelectrolytesolutionsforlithiumandlithiumionbatteriesqualitycontrolandminimizingcontaminationlevel[J].J .PowerSources,1999,81~82:119~122.

[25] AurbachD ,ZabanA ,Ein_EliY .ThestudyofelectrolytesolutionsbasedonethyleneanddiethylcarbonatesforrechargeableLibatteries[J].J .Elelctrochem.Soc.,1995,142:2873.

[26] AurbachD ,GottliebHE .Theelectrochemicalbehaviorofselectedpolaraproticsystem[J].ElectrochemActa,1989,34:141.

[27] AurbachD ,GoferY ,Ben_ZionM .Thebehavioroflithiumelectrodesinpropyleneandethylenecarbonate:themajorfactorsinfluenceLicyclingefficiency[J].J.Electroanal.Chem.,1992,339:451.

[28] HeiderU ,OestenR ,JungnitzM .Challengeinmanufacturingelectrolytesolutionsforlithiumandlithiumionbatteriesqualitycontrolandminimizingcontaminationlevel[J].J .PowerSources,1999,81~82:119~122.

[29] FelixJoho,BeatRykart,RomanImhof.Keyfactorsforthecyclingstabilityofgraphiteintercalationelec trodesforlithium_ionbatteries[J].J .PowerSources,1999,81~82:243~247.LiC6/electrolyte/Lisys tem.

[30] M interKC ,HodalT ,AppelWK ,WinterM .,BesenhardJO .Fluorinatedorganicsolventsinelec trolytesforlithiumioncells[J].JournalofPowerSources.Adv.Mater.,2001,97~98:595.

[31] WinterM ,NovakP .Graphitesforlithium_ioncells:thecorrelatinofthefirst_cycleschargelosswiththeBrunauer_Emmett_Tellersurfacearea[J].J .Electrochem.Soc,1998,145:428

Share

COinS
 
 

To view the content in your browser, please download Adobe Reader or, alternately,
you may Download the file to your hard drive.

NOTE: The latest versions of Adobe Reader do not support viewing PDF files within Firefox on Mac OS and if you are using a modern (Intel) Mac, there is no official plugin for viewing PDF files within the browser window.