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Corresponding Author

Bing-Liang WU(blwujin@yahoo.com.cn)

Abstract

A novel microcavity Ag|AgCl electrode was fabricated to construct the micro-interface of two immiscible electrolyte solutions(ITIES). The transfer reactions of K+ ion facilitated by DB18C6 across the water/1,2-DCE interface was investigated with the three-electrodes system. The corresponding reaction parameters were derived from the voltammetric data. The results showed that the microcavity electrode would be a useful and efficient tool to investigate the charge transfer reactions at ITIES.

Keywords

Micro-cavity electrode, ITIES, Facilitated ion transfer

Publication Date

2002-08-28

Online Available Date

2002-08-28

Revised Date

2002-08-20

Received Date

2001-11-19

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