•  
  •  
 

Corresponding Author

Cui-wei DU

Abstract

The structure, physical characteristics and electrochemical properties of the natural graphite produced in Shandong province have been studied. The result of X-ray diffraction showed that the graphite consisted of hexagonal structure and rhombic structure (30% rhombic structure). It was fine crystal graphite. Used as a negative material of Lithium ion battery, the natural graphite showed excellent voltage and high energy capacity, but poor compatibility with electrolyte solution containing propylene carbonate (PC) for its own structure limitation.

Keywords

Lithium ion secondary batteries, Anode Materials, Natural Graphite, Surface heat treatment

Publication Date

2002-11-28

Online Available Date

2002-11-28

Revised Date

2002-11-28

Received Date

2002-11-28

References

[1] AbrahamKM .Directionsinsecondarylithiumbatteryresearchanddevelopment[J].ElectrochimicaActa.,1993,38(9):1233~1248.

[2] HUShao_jie,XUBao_bo.DevelopmentandprospectofLi_ionbatteryindustry[J].Batterybimonthly,2000,30,(4):171~174.

[3] TANGZhi_yuan,ZAIYu_mei,ZHANGXin_guo,etal.Studyoflithium_storedpropertiesandparticalstruc turesofgraphitepowder[J].ChineseJournalofPowerSources,2001,25(1):29~31.

[4] TsumuraT ,KatanosakaA ,SoumaI ,etal.Surfacemodificationofnaturalgraphiteparticlesforlithiumionbatteries[J].SolidStataIonics,2000,135:209~212.

[5] DUCui_wei,CHENYan_bin,WUYin_shun,etal.Thestudyoflithium_ionbatteriesnone_carbonnegativematerials[A].The24 thChemicalandPhysicalBatteriesAnnualMeeting[C]Harbin,2000,8,(11~15).294~295.

[6] WUGuo_liang.StatusanddevelopmentonnegativeactivematerialforLithium_ionbatteris[J].Batterybi monthly,2001,31(2):54~57.

[7] PeledE ,EshkenaziV ,RosenbregY ,etal.StudyoflithiuminsertioninhardcarbonmadefromcottonWool[J].JPowerSources,1998,76:153~158.

[8] ZhengT ,LiuYH ,FullerEW ,etal.Lithiuminsertioninhighcapacitycarbonaceousmaterials[J].JElec trochemSoc.,1995,142(8):2581~2590.

[9] ShiH ,BarkerJ ,SaidiMY ,etal.Structureandlithiumintercalationpropertiesofsyntheticandnaturalgraphite[J].J .Electrochem.Soc.,1996,143(11):3466~3472.

Share

COinS
 
 

To view the content in your browser, please download Adobe Reader or, alternately,
you may Download the file to your hard drive.

NOTE: The latest versions of Adobe Reader do not support viewing PDF files within Firefox on Mac OS and if you are using a modern (Intel) Mac, there is no official plugin for viewing PDF files within the browser window.