Study for the Cathodic Behavior of Active Chlorine on 316L SS Electrode Surface

Authors

Hui YU, Chemistry Department of Shantou Universitry,Shantou 515063,China;Department of Chemistry,State Key Laboratory for Physical Chemistry of Solid Surfaces, Institute o;
Ming-xian SUN, 725 Research Institute Qingdao Branch,Qingdao 266071,China,;
Yan MA, 725 Research Institute Qingdao Branch,Qingdao 266071,China,;
Xiao-bin WANG, Qingdao Supervision & Inspection Institute of Product Quality, Qingdao 266071,China);

Abstract

The cathodic reducing reactions of active chlorine on 316L SS electrode surface have been investigated by electrochemical techniques. The open circuit potential shifted positively and the limited diffusion current density increased significantly with the increasing content of active chlorine in the 3.5%sodium chloride solution. The two cathodic reduction processes of HClO and ClO- exhibited on the surface of electrode with the active chlorine added to the 3.5%sodium chloride solution and the corresponding potentials of the two reducing reactions were confirmed. The linear relationship of the mass transport_limited Faradaic current, Id vs. the square root of the angular velocity of the rotating disc following indicates that the overall active chlorine reducing reactions is controlled by a mass transport control process.

DOI Link

https://doi.org/10.61558/2993-074X.1486

Publication Date

2003-02-28

Online Available Date

2003-02-28

Revised Date

2003-02-28

Received Date

2003-02-28

Recommended Citation

Hui YU, Ming-xian SUN, Yan MA, Xiao-bin WANG. Study for the Cathodic Behavior of Active Chlorine on 316L SS Electrode Surface[J]. Journal of Electrochemistry, 2003 , 9(1): 66-70.
DOI: 10.61558/2993-074X.1486
Available at: https://jelectrochem.xmu.edu.cn/journal/vol9/iss1/12

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