Abstract
Electrochemical behavior of methyl green in different kinds of solution and the supramolecule system of methyl green_cyclodextrin were studied.Inclusion constants of four cyclodextrin with emthyl green were determined by “electric current method”.The order of inclusion ability is HP_β_CD,β_CD,SBE_β_CD and CM_β_CD.The molar ratio of inclusion complexes of methyl green with CDs is 1:2. A possible mechanism was reported for methyl green.
Keywords
Methyl green, Cyclodextrin, Electric current method, Supermolecule System
Publication Date
2003-08-28
Online Available Date
2003-08-28
Revised Date
2003-08-28
Received Date
2003-08-28
Recommended Citation
Yu-jing GUO, Jing-hao PAN, Chun-hua GUO, Hong-lian ZHENG.
Study on the Electrochemical Behavior of Methy1 Green and Methy1 Green-Cyclodextrin Supramolecule System[J]. Journal of Electrochemistry,
2003
,
9(3): Article 19.
DOI: 10.61558/2993-074X.3320
Available at:
https://jelectrochem.xmu.edu.cn/journal/vol9/iss3/19
References
[1] NakamuraNobuyuki.Productionandapplicationofcyclodextrins[J].Kagakukoygo.1984,35(7):627～634.
[2] LiuShu_qin(刘淑琴),FanHui_zhi(樊惠芝),PanJing_hao(潘景浩).ElectrochemicalofCyclodextrinsandItsInclusionComplexes[M ].Taiyuan:ShamxiScienceandTechnologyPress(inChinese),1997.
[3] YaoXiu_ren(姚修仁),ZhangLi_qun(张立群).SpectraofPolarographicCatalyticCurrent(极谱催化波图谱)[M].Beijing:GeologyPress(inChinese),1988.
[4] GaoXiao_xia(高小霞).PolarographicCatalyticCurrent(极谱催化波)[M ].Beijing:SciencePress(inChi nese),1991.
[5] DongShao_jun(董绍俊),ZhangDong_hai(张东海).StudyoftheInclusionComplexesofCyclodextrinbyCyclicVoltammetry[J].ActaChimicaSinica(inChinese),1988,46:335～339.
[6] WangXP ,PanJH ,LiWH .StudyofTAPPwithcyclodextrinsbypolarography[J].Talanta,2001,54:805.
[7] LavironE .Adsorptionautoinhibitionandautocatalysisinpolarographyandinlinerpotentialsweepvoltammetry[J].J .ElectronalChem,1974,52:370.
[8] BardAJ,FaouknerLR .ElectrochemicalMethods(FundamentalsandApplication)[M ].Newyork:1980,525:96
[9] DingShijia(丁世家),ZhangZuxun(张祖训).Investigationsonpolarographywithlinearlychangingpotential(XV)———TheAdsorptiveComplexwaveofCu(Ⅱ)_L_Adrenaline[J].J .Chem.ChineseUniversity(inChi nese),1991,12(5):598.
